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In thermodynamics, the ebullioscopic constant K b relates molality b to boiling point elevation. [1] It is the ratio of the latter to the former: = i is the van 't Hoff factor, the number of particles the solute splits into or forms when dissolved. b is the molality of the solution.
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1] Lauric acid: 298.9 44 –3.9 Acetic acid: 1.04 117.9 3.14 16.6 –3.90 K b [1] K f [2] Acetone: 0.78 56.2 1.67 –94.8 K b [3] Benzene: 0.87 80.1 2.65 5.5 –5.12 K b & K f [2] Bromobenzene: 1.49 156.0 6. ...
The result is that in dilute ideal solutions, the extent of boiling-point elevation is directly proportional to the molal concentration (amount of substance per mass) of the solution according to the equation: [2] ΔT b = K b · b c. where the boiling point elevation, is defined as T b (solution) − T b (pure solvent).
Melting point: None; decomposes at 186 °C (367 °F; 459 K) ... Sucrose, a disaccharide, is a ... The sugar syrup is then concentrated by boiling under a vacuum and ...
Vidal ebullioscope. In physics, an ebullioscope (from Latin ēbullīre 'to boil') is an instrument for measuring the boiling point of a liquid.This can be used for determining the alcoholic strength of a mixture, or for determining the molecular weight of a non-volatile solute based on the boiling-point elevation.
The term molality is formed in analogy to molarity which is the molar concentration of a solution. The earliest known use of the intensive property molality and of its adjectival unit, the now-deprecated molal, appears to have been published by G. N. Lewis and M. Randall in the 1923 publication of Thermodynamics and the Free Energies of Chemical Substances. [3]
For liquid solutions, the osmotic coefficient is often used to calculate the salt activity coefficient from the solvent activity, or vice versa. For example, freezing point depression measurements, or measurements of deviations from ideality for other colligative properties, allows calculation of the salt activity coefficient through the osmotic coefficient.
This is a list of the various reported boiling points for the elements, with recommended values to be used elsewhere on Wikipedia. ... all values refer to the normal ...