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Thermal expansion generally decreases with increasing bond energy, which also has an effect on the melting point of solids, so high melting point materials are more likely to have lower thermal expansion. In general, liquids expand slightly more than solids. The thermal expansion of glasses is slightly higher compared to that of crystals. [5]
When the cause of the convection is unspecified, convection due to the effects of thermal expansion and buoyancy can be assumed. Convection may also take place in soft solids or mixtures where particles can flow. Thermal image of a newly lit Ghillie kettle. The plume of hot air resulting from the convection current is visible.
In thermodynamics and fluid mechanics, the compressibility (also known as the coefficient of compressibility [1] or, if the temperature is held constant, the isothermal compressibility [2]) is a measure of the instantaneous relative volume change of a fluid or solid as a response to a pressure (or mean stress) change.
To distinguish these two thermal expansion equations of state, the latter one is called pressure-dependent thermal expansion equation of state. To deveop the pressure-dependent thermal expansion equation of state, in an compression process at room temperature from (V 0, T 0, P 0) to (V 1, T 0,P 1), a general form of volume is expressed as
The cooling produced in the Joule–Thomson expansion makes it a valuable tool in refrigeration. [8] [20] The effect is applied in the Linde technique as a standard process in the petrochemical industry, where the cooling effect is used to liquefy gases, and in many cryogenic applications (e.g. for the production of liquid oxygen, nitrogen, and ...
Temperature gradients, thermal expansion or contraction and thermal shocks are things that can lead to thermal stress. This type of stress is highly dependent on the thermal expansion coefficient which varies from material to material. In general, the greater the temperature change, the higher the level of stress that can occur.
An example of the effects of anharmonicity is the thermal expansion of solids, which is usually studied within the quasi-harmonic approximation. Studying vibrating anharmonic systems using quantum mechanics is a computationally demanding task because anharmonicity not only makes the potential experienced by each oscillator more complicated, but ...
Negative thermal expansion (NTE) is an unusual physicochemical process in which some materials contract upon heating, rather than expand as most other materials do. The most well-known material with NTE is water at 0 to 3.98 °C. Also, the density of solid water (ice) is lower than the density of liquid water at standard pressure.