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3 Fe(OH) 2 → Fe 3 O 4 + H 2 + 2 H 2 O. Anions such as selenite and selenate can be easily adsorbed on the positively charged surface of iron(II) hydroxide, where they are subsequently reduced by Fe 2+. The resulting products are poorly soluble (Se 0, FeSe, or FeSe 2).
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The tables below provides information on the variation of solubility of different substances ... Fe(OH) 2: 5.255×10 −5: Iron(II) nitrate: Fe(NO 3) 2 ·6H 2 O: 113: ...
Iron(III) oxide-hydroxide or ferric oxyhydroxide [2] is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH). The compound is often encountered as one of its hydrates, FeO(OH) ·n H 2 O [rust]. The monohydrate FeO(OH) · H 2 O is often referred to as iron(III) hydroxide Fe(OH) 3, [3] hydrated iron oxide, yellow iron oxide ...
When Fe 2 O 3 ·H 2 O is heated, it loses its water of hydration. Further heating at 1670 K converts Fe 2 O 3 to black Fe 3 O 4 (Fe II Fe III 2 O 4), which is known as the mineral magnetite. Fe(O)OH is soluble in acids, giving [Fe(H 2 O) 6] 3+. In concentrated aqueous alkali, Fe 2 O 3 gives [Fe(OH) 6] 3−. [12]
Fe 0 + 2 H + → Fe 2+ + H 2. Iron(II) is oxidized by hydrogen peroxide to iron(III), forming a hydroxyl radical and a hydroxide ion in the process. This is the Fenton reaction. Iron(III) is then reduced back to iron(II) by another molecule of hydrogen peroxide, forming a hydroperoxyl radical and a proton.
Iron(II) acetate describes compounds with formula Fe(CH 3 CO 2) 2 ·(H 2 O) x where x can be 0 (anhydrous) or 4 (tetrahydrate). The anhydrous compound is a white solid, although impure samples can be slightly colored. [1] The tetrahydrate is light green solid that is highly soluble in water.
Solubility of iron species is directly governed by the solution's pH. Fe 3+ is about 100 times less soluble than Fe 2+ in natural water at near-neutral pH, the ferric ion concentration is the limiting factor for the reaction rate. Under high pH conditions, the stability of the H 2 O 2 is also affected, resulting in its self-decomposition. [14]