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If one considers the text of every book ever published as a sequence, with each symbol being the text of a complete book, and if there are N published books, and each book is only published once, the estimate of the probability of each book is 1/N, and the entropy (in bits) is −log 2 (1/N) = log 2 (N).
Equivalently, the min-entropy () is the largest real number b such that all events occur with probability at most . The name min-entropy stems from the fact that it is the smallest entropy measure in the family of Rényi entropies. In this sense, it is the strongest way to measure the information content of a discrete random variable.
Despite the foregoing, there is a difference between the two quantities. The information entropy Η can be calculated for any probability distribution (if the "message" is taken to be that the event i which had probability p i occurred, out of the space of the events possible), while the thermodynamic entropy S refers to thermodynamic probabilities p i specifically.
In the mathematical theory of probability, the entropy rate or source information rate is a function assigning an entropy to a stochastic process. For a strongly stationary process, the conditional entropy for latest random variable eventually tend towards this rate value.
A new approach to the problem of entropy evaluation is to compare the expected entropy of a sample of random sequence with the calculated entropy of the sample. The method gives very accurate results, but it is limited to calculations of random sequences modeled as Markov chains of the first order with small values of bias and correlations ...
However, the heat transferred to or from the surroundings is different as well as its entropy change. We can calculate the change of entropy only by integrating the above formula. To obtain the absolute value of the entropy, we consider the third law of thermodynamics: perfect crystals at the absolute zero have an entropy =.
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process.
The joint information is equal to the mutual information plus the sum of all the marginal information (negative of the marginal entropies) for each particle coordinate. Boltzmann's assumption amounts to ignoring the mutual information in the calculation of entropy, which yields the thermodynamic entropy (divided by the Boltzmann constant).