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Residual entropy is the difference in entropy between a non-equilibrium state and crystal state of a substance close to absolute zero. This term is used in condensed matter physics to describe the entropy at zero kelvin of a glass or plastic crystal referred to the crystal state, whose entropy is zero according to the third law of thermodynamics .
Some crystals form defects which cause a residual entropy. This residual entropy disappears when the kinetic barriers to transitioning to one ground state are overcome. [8] With the development of statistical mechanics, the third law of thermodynamics (like the other laws) changed from a fundamental law (justified by experiments) to a derived ...
Various principles have been proposed by diverse authors for over a century. According to Glansdorff and Prigogine (1971, page 15), [9] in general, these principles apply only to systems that can be described by thermodynamical variables, in which dissipative processes dominate by excluding large deviations from statistical equilibrium.
The statistical entropy perspective was introduced in 1870 by Austrian physicist Ludwig Boltzmann, who established a new field of physics that provided the descriptive linkage between the macroscopic observation of nature and the microscopic view based on the rigorous treatment of large ensembles of microscopic states that constitute ...
The statistical definition of entropy defines it in terms of the statistics of the motions of the microscopic constituents of a system — modelled at first classically, e.g. Newtonian particles constituting a gas, and later quantum-mechanically (photons, phonons, spins, etc.). The two approaches form a consistent, unified view of the same ...
The residual entropy of a fluid has some special significance. In 1976, Yasha Rosenfeld published a landmark paper, showing that the transport coefficients of pure liquids, when expressed as functions of the residual entropy, can be treated as monovariate functions, rather than as functions of two variables (i.e. temperature and pressure, or ...
This broader terminology is used when quantiles are used to parameterize continuous probability distributions. Moreover, some software programs (including Microsoft Excel) regard the minimum and maximum as the 0th and 100th percentile, respectively. However, this broader terminology is an extension beyond traditional statistics definitions.
To highlight the fact that order and disorder are commonly understood to be measured in terms of entropy, below are current science encyclopedia and science dictionary definitions of entropy: A measure of the unavailability of a system's energy to do work; also a measure of disorder; the higher the entropy the greater the disorder.