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Sulfur trioxide (alternative spelling sulphur trioxide) is the chemical compound with the formula SO 3. ... β-SO 3, like the alpha form, is fibrous but of different ...
α-Olefin sulfonates are produced by sulfonation of alpha-olefins, typically using sulfur trioxide. Subsequent alkaline hydrolysis gives a mixture of alkene sulfonates (60-65%) and hydroxyalkane sulfonates (35-40%). The commercially available olefin sulfonates are mostly solutions with about 40% active ingredient content. [4] [5]
Sulfur trioxide, SO 3, a chemical compound of sulfur and the anhydride of sulfuric acid; Sulfite, SO 2− 3, a chemical ion composed of sulfur and oxygen with a 2− charge; SO(3), the special orthogonal group in 3 dimensions; the rotations that can be given an object in 3-space; Star Ocean: Till the End of Time, the third main game in the Star ...
[4] α-Sulfur is the predominant form found in "flowers of sulfur", "roll sulfur" and "milk of sulfur". [19] It contains S 8 puckered rings, alternatively called a crown shape. The S–S bond lengths are all 203.7 pm and the S-S-S angles are 107.8° with a dihedral angle of 98°. [ 16 ]
The two principal sulfur oxides are obtained by burning sulfur: S + O 2 → SO 2 (sulfur dioxide) 2 SO 2 + O 2 → 2 SO 3 (sulfur trioxide). Many other sulfur oxides are observed including the sulfur-rich oxides include sulfur monoxide, disulfur monoxide, disulfur dioxides, and higher oxides containing peroxo groups.
Oleum (Latin oleum, meaning oil), or fuming sulfuric acid, is a term referring to solutions of various compositions of sulfur trioxide in sulfuric acid, or sometimes more specifically to disulfuric acid (also known as pyrosulfuric acid). [1] Oleums can be described by the formula ySO 3 ·H 2 O where y is the
Sulfur trioxide is the active ingredient in many sulfonation reactions. Typical conditions involve heating the aromatic compound with sulfuric acid: [2] C 6 H 6 + H 2 SO 4 → C 6 H 5 SO 3 H + H 2 O. Sulfur trioxide or its protonated derivative is the actual electrophile in this electrophilic aromatic substitution.
At 120 °C, hydroxylammonium sulfate begins to decompose to sulfur trioxide, nitrous oxide, water, and ammonia [dubious – discuss]: 2 (NH 3 OH) 2 SO 4 → 2 SO 3 + N 2 O + 2 NH 3 + 5 H 2 O. The reaction is exothermic above 138 °C, and is most exothermic at 177 °C. [3]