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The strain energy in the form of elastic deformation is mostly recoverable in the form of mechanical work. For example, the heat of combustion of cyclopropane (696 kJ/mol) is higher than that of propane (657 kJ/mol) for each additional CH 2 unit. Compounds with unusually large strain energy include tetrahedranes, propellanes, cubane-type ...
There are situations where seemingly identical conformations are not equal in strain energy. Syn-pentane strain is an example of this situation. There are two different ways to put both of the bonds the central in n-pentane into a gauche conformation, one of which is 3 kcal mol −1 higher in energy than the other. [1]
The J-integral represents a way to calculate the strain energy release rate, or work per unit fracture surface area, in a material. [1] The theoretical concept of J-integral was developed in 1967 by G. P. Cherepanov [2] and independently in 1968 by James R. Rice, [3] who showed that an energetic contour path integral (called J) was independent of the path around a crack.
Castigliano's method for calculating displacements is an application of his second theorem, which states: If the strain energy of a linearly elastic structure can be expressed as a function of generalised force Q i then the partial derivative of the strain energy with respect to generalised force gives the generalised displacement q i in the direction of Q i.
For an isotropic hyperelastic material, the function relates the energy stored in an elastic material, and thus the stress–strain relationship, only to the three strain (elongation) components, thus disregarding the deformation history, heat dissipation, stress relaxation etc.
Strain energy density consists of two components - volumetric or dialational and distortional. Volumetric component is responsible for change in volume without any change in shape. Distortional component is responsible for shear deformation or change in shape.
Strain energy release rate per unit fracture surface area is calculated by J-integral method which is a contour path integral around the crack tip where the path begins and ends on either crack surfaces. J-toughness value signifies the resistance of the material in terms of amount of stress energy required for a crack to grow.
For rubber and biological materials, more sophisticated models are necessary. Such materials may exhibit a non-linear stress–strain behaviour at modest strains, or are elastic up to huge strains. These complex non-linear stress–strain behaviours need to be accommodated by specifically tailored strain-energy density functions.