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In coordination chemistry, the ligand cone angle (θ) is a measure of the steric bulk of a ligand in a transition metal coordination complex. It is defined as the solid angle formed with the metal at the vertex of a cone and the outermost edge of the van der Waals spheres of the ligand atoms at the perimeter of the base of the cone.
In the case of lines, the cone extends infinitely far in both directions from the apex, in which case it is sometimes called a double cone. Either half of a double cone on one side of the apex is called a nappe. The axis of a cone is the straight line passing through the apex about which the base (and the whole cone) has a circular symmetry.
Diagram showing a section through the centre of a cone (1) subtending a solid angle of 1 steradian in a sphere of radius r, along with the spherical "cap" (2). The external surface area A of the cap equals r2 only if solid angle of the cone is exactly 1 steradian. Hence, in this figure θ = A/2 and r = 1.
The pyrometric cone is "A pyramid with a triangular base and of a defined shape and size; the "cone" is shaped from a carefully proportioned and uniformly mixed batch of ceramic materials so that when it is heated under stated conditions, it will bend due to softening, the tip of the cone becoming level with the base at a definitive temperature.
Skeletal structural formula of Vitamin B 12.Many organic molecules are too complicated to be specified by a molecular formula.. The structural formula of a chemical compound is a graphic representation of the molecular structure (determined by structural chemistry methods), showing how the atoms are possibly arranged in the real three-dimensional space.
In geometry, a net of a polyhedron is an arrangement of non-overlapping edge-joined polygons in the plane which can be folded (along edges) to become the faces of the polyhedron. Polyhedral nets are a useful aid to the study of polyhedra and solid geometry in general, as they allow for physical models of polyhedra to be constructed from ...
Chemical reaction network theory is an area of applied mathematics that attempts to model the behaviour of real-world chemical systems. Since its foundation in the 1960s, it has attracted a growing research community, mainly due to its applications in biochemistry and theoretical chemistry .
In theoretical chemistry, an energy profile is a theoretical representation of a chemical reaction or process as a single energetic pathway as the reactants are transformed into products. This pathway runs along the reaction coordinate , which is a parametric curve that follows the pathway of the reaction and indicates its progress; thus ...