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In stereochemistry, prochiral molecules are those that can be converted from achiral to chiral in a single step. [1] [2] An achiral species which can be converted to a chiral in two steps is called proprochiral. [2] If two identical substituents are attached to an sp 3-hybridized atom, the descriptors pro-R and pro-S are used to distinguish ...
The first intended product was the Victa R-2, a four-seat single-engine light aircraft designed by Luigi Pellarini. [ 1 ] [ 2 ] [ 3 ] Pellarini's design was a low-winged, all metal tractor configuration monoplane with a T-tail , powered by a 180 hp (130 kW) Lycoming O-360 flat-four piston engine driving a constant-speed propeller .
Enantioselective ketone reductions convert prochiral ketones into chiral, non-racemic alcohols and are used heavily for the synthesis of stereodefined alcohols. [1] Carbonyl reduction, the net addition of H 2 across a carbon-oxygen double bond, is an important way to prepare
Chiral molecules in the receptors in our noses can tell the difference between these things. Chirality affects biochemical reactions, and the way a drug works depends on what kind of enantiomer it is. Many drugs are chiral and it is important that the shape of the drug matches the shape of the cell receptor it is meant to affect.
Pro Modified, also known as Pro Mod, is a class or division in the sport of drag racing used in the NHRA and FIA (quarter-mile) and the Professional Drag Racers Association (PDRA) (eighth-mile). It is similar to the Top Doorslammer class as defined by the ANDRA .
In organic chemistry, kinetic resolution is a means of differentiating two enantiomers in a racemic mixture.In kinetic resolution, two enantiomers react with different reaction rates in a chemical reaction with a chiral catalyst or reagent, resulting in an enantioenriched sample of the less reactive enantiomer. [1]
The Corey–Itsuno reduction, also known as the Corey–Bakshi–Shibata (CBS) reduction, is a chemical reaction in which a prochiral ketone is enantioselectively reduced to produce the corresponding chiral, non-racemic alcohol.
A planar chiral derivative of ferrocene, used for kinetic resolution of some racemic secondary alcohols [1]. This term is used in chemistry contexts, [2] e.g., for a chiral molecule lacking an asymmetric carbon atom, but possessing two non-coplanar rings that are each dissymmetric and which cannot easily rotate about the chemical bond connecting them: 2,2'-dimethylbiphenyl is perhaps the ...