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Thallium tends to form the +3 and +1 oxidation states. ... A thallium atom has 81 electrons, arranged in the electron configuration [Xe]4f 14 5d 10 6s 2 6p 1; ...
As an approximate rule, electron configurations are given by the Aufbau principle and the Madelung rule. However there are numerous exceptions; for example the lightest exception is chromium, which would be predicted to have the configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 4 4s 2 , written as [Ar] 3d 4 4s 2 , but whose actual configuration given ...
Boron oxide (B 2 O 3) is slightly acidic, aluminium and gallium oxide (Al 2 O 3 and Ga 2 O 3 respectively) are amphoteric, indium(III) oxide (In 2 O 3) is nearly amphoteric, and thallium(III) oxide (Tl 2 O 3) is a Lewis base because it dissolves in acids to form salts.
General inorganic chemistry texts often put scandium (Sc), yttrium (Y), lanthanum (La), and actinium (Ac) in group 3, so that Ce–Lu and Th–Lr become the f-block between groups 3 and 4; this was based on incorrectly measured electron configurations from history, [25] and Lev Landau and Evgeny Lifshitz already considered it incorrect in 1948 ...
Note that these electron configurations are given for neutral atoms in the gas phase, which are not the same as the electron configurations for the same atoms in chemical environments. In many cases, multiple configurations are within a small range of energies and the small irregularities that arise in the d- and f-blocks are quite irrelevant ...
Other effects of the d-block contraction are that the Ga 3+ ion is smaller than expected, being closer in size to Al 3+.Care must be taken in interpreting the ionization potentials for indium and thallium, since other effects, e.g. the inert-pair effect, become increasingly important for the heavier members of the group.
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Thallium (indium's heavier homolog) shows an even stronger effect, causing oxidation to thallium(I) to be more probable than to thallium(III), [30] whereas gallium (indium's lighter homolog) commonly shows only the +3 oxidation state. Thus, although thallium(III) is a moderately strong oxidizing agent, indium(III) is not, and many indium(I ...