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When studying or discussing explosive safety, or the safety of systems containing explosives, the terms deflagration, detonation and deflagration-to-detonation transition (commonly referred to as DDT) must be understood and used appropriately to convey relevant information.
The simplest theory to predict the behaviour of detonations in gases is known as the Chapman–Jouguet (CJ) condition, developed around the turn of the 20th century. This theory, described by a relatively simple set of algebraic equations, models the detonation as a propagating shock wave accompanied by exothermic heat release.
The phenomenon is exploited in pulse detonation engines, because a detonation produces a more efficient combustion of the reactants than a deflagration does, i.e. giving a higher yields. Such engines typically employ a Shchelkin spiral in the combustion chamber to facilitate the deflagration to detonation transition. [2] [3]
The exploding-bridgewire detonator (EBW, also known as exploding wire detonator) is a type of detonator used to initiate the detonation reaction in explosive materials, similar to a blasting cap because it is fired using an electric current. EBWs use a different physical mechanism than blasting caps, using more electricity delivered much more ...
In more detail (in the ZND model) in the frame of the leading shock of the detonation wave, gases enter at supersonic velocity and are compressed through the shock to a high-density, subsonic flow. This sudden change in pressure initiates the chemical (or sometimes, as in steam explosions, physical) energy release. The energy release re ...
a small amount of a more powerful secondary explosive, directly in contact with the primary, and called "base" or "output" explosive, able to carry out the detonation through the casing of the detonator to the main explosive device to activate it. Explosives commonly used as primary in detonators include lead azide, lead styphnate, tetryl, and DDNP
In detonation synthesis, nanodiamonds form under pressures greater than 15 GPa and temperatures greater than 3000K in the absence of oxygen to prevent the oxidation of diamond nanoparticles. [10] The rapid cooling of the system increases nanodiamond yields as diamond remains the most stable phase under such conditions.
Detonation velocities are of limited value in assessing the reaction rates of nitrocellulose propellants formulated to avoid detonation. Although the slower reaction is often described as burning because of similar gaseous end products at elevated temperatures, the decomposition differs from combustion in an oxygen atmosphere.