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Many other fundamental quantities in science are time derivatives of one another: force is the time derivative of momentum; power is the time derivative of energy; electric current is the time derivative of electric charge; and so on. A common occurrence in physics is the time derivative of a vector, such as velocity or displacement. In dealing ...
The second-order phase transition was for a while controversial, as it seems to require two sheets of the Gibbs free energy to osculate exactly, which is so unlikely as to never occur in practice. Cornelis Gorter replied the criticism by pointing out that the Gibbs free energy surface might have two sheets on one side, but only one sheet on the ...
Besides structural order, one may consider charge ordering, spin ordering, magnetic ordering, and compositional ordering. Magnetic ordering is observable in neutron diffraction. It is a thermodynamic entropy concept often displayed by a second-order phase transition. Generally speaking, high thermal energy is associated with disorder and low ...
The temperature approaches a linear function because that is the stable solution of the equation: wherever temperature has a nonzero second spatial derivative, the time derivative is nonzero as well. The heat equation implies that peaks ( local maxima ) of u {\displaystyle u} will be gradually eroded down, while depressions ( local minima ...
The second step with OH − is much faster, so the overall rate is independent of the concentration of OH −. In contrast, the alkaline hydrolysis of methyl bromide (CH 3 Br) is a bimolecular nucleophilic substitution (S N 2) reaction in a single bimolecular step. Its rate law is second-order: r = k[R−Br][OH −].
A unit of time is any particular time interval, used as a standard way of measuring or expressing duration. The base unit of time in the International System of Units (SI), and by extension most of the Western world , is the second , defined as about 9 billion oscillations of the caesium atom.
The most common is the change in space and time of the concentration of one or more chemical substances: local chemical reactions in which the substances are transformed into each other, and diffusion which causes the substances to spread out over a surface in space. Reaction–diffusion systems are naturally applied in chemistry. However, the ...
For example, the stress–energy tensor is a second-order tensor field containing energy–momentum densities, energy–momentum fluxes, and shear stresses, of a mass-energy distribution. The differential form of energy–momentum conservation in general relativity states that the covariant divergence of the stress-energy tensor is zero: T μ ...