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Vanadium was discovered in Mexico in 1801 by the Spanish mineralogist Andrés Manuel del Río. Del Río extracted the element from a sample of Mexican "brown lead" ore, later named vanadinite. He found that its salts exhibit a wide variety of colors, and as a result, he named the element panchromium (Greek: παγχρώμιο "all colors").
Vanadium pentoxide is a commercially important catalyst for the production of sulfuric acid, a reaction that exploits the ability of vanadium oxides to undergo redox reactions. [2] The vanadium redox battery utilizes all four oxidation states: one electrode uses the +5/+4 couple and the other uses the +3/+2 couple. Conversion of these oxidation ...
A vanadium ore or vanadium-rich residue is treated with sodium carbonate and an ammonium salt to produce sodium metavanadate, NaVO 3. This material is then acidified to pH 2–3 using H 2 SO 4 to yield a precipitate of "red cake" (see above). The red cake is then melted at 690 °C to produce the crude V 2 O 5.
Vanadium was discovered in 1801 by the Spanish mineralogist Andrés Manuel del Río. Del Río extracted the element from a sample of Mexican "brown lead" ore, later named vanadinite. He found that its salts exhibit a wide variety of colors, and as a result he named the element panchromium (Greek: παγχρώμιο "all colors").
It is composed (by weight) of 73.15% lead, 10.79% vanadium, 13.56% oxygen, and 2.50% chlorine. Each structural unit of vanadinite contains a chlorine ion surrounded by six divalent lead ions at the corners of a regular octahedron , with one of the lead ions provided by an adjoining vanadinite molecule.
A mine was established in very short time by the Vanadium Corporation of America. By 1914 75% of the world vanadium ore production was coming from the Minas Ragra in Peru, making the mine the world leading producer of vanadium. [3] With the production of vanadium as side product of uranium mining from carnotite the mine had to close in 1955.
In chemistry, a vanadate is an anionic coordination complex of vanadium. Often vanadate refers to oxoanions of vanadium, most of which exist in its highest oxidation state of +5. The complexes [V(CN) 6] 3− and [V 2 Cl 9] 3− are referred to as hexacyanovanadate(III) and nonachlorodivanadate(III), respectively.
Vanadium oxide mainly refers to: Vanadium(II) oxide (vanadium monoxide), VO; Vanadium(III) oxide (vanadium sesquioxide or trioxide), V 2 O 3; Vanadium(IV) oxide (vanadium dioxide), VO 2; Vanadium(V) oxide (vanadium pentoxide), V 2 O 5; Various other distinct phases include: Phases with the general formula V n O 2n+1 exist between V 2 O 5 and VO 2.