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The systematic IUPAC name is not always the preferred IUPAC name, for example, lactic acid is a common, and also the preferred, name for what systematic rules call 2-hydroxypropanoic acid. This list is ordered by the number of carbon atoms in a carboxylic acid.
Triacetate is derived from cellulose by acetylating cellulose with acetic acid and/or acetic anhydride. Acetylation converts hydroxyl groups in cellulose to acetyl groups, which renders the cellulose polymer much more soluble in organic solvents. The cellulose acetate is dissolved in a mixture of dichloromethane and methanol for spinning.
Acetic anhydride, or ethanoic anhydride, is the chemical compound with the formula (CH 3 CO) 2 O. Commonly abbreviated Ac 2 O, it is the simplest isolable anhydride of a carboxylic acid and is widely used as a reagent in organic synthesis. It is a colorless liquid that smells strongly of acetic acid, which is formed by its reaction with ...
For example, at room temperature, in a 1-molar solution of acetic acid, only 0.001% of the acid are dissociated (i.e. 10 −5 moles out of 1 mol). Electron-withdrawing substituents, such as -CF 3 group, give stronger acids (the pK a of acetic acid is 4.76 whereas trifluoroacetic acid, with a trifluoromethyl substituent, has a pK a of 0.23).
Acetic acid injection into a tumor has been used to treat cancer since the 1800s. [53] [54] Acetic acid is used as part of cervical cancer screening in many areas in the developing world. [55] The acid is applied to the cervix and if an area of white appears after about a minute the test is positive. [55]
However, acetic acid is usually also formed as a by-product of the reaction, so that the solvent is ultimately a mixture of methylene chloride, acetic anhydride and acetic acid. A very rare heterogeneous process is the fiber acetate process, which is only used for the production of cellulose triacetate as an end product.
Traditionally, acetaldehyde was mainly used as a precursor to acetic acid. This application has declined because acetic acid is produced more efficiently from methanol by the Monsanto and Cativa processes. Acetaldehyde is an important precursor to pyridine derivatives, pentaerythritol, and crotonaldehyde.
It is classified as an ester that is formed from 1-octanol (octyl alcohol) and acetic acid. It is found in oranges, grapefruits, and other citrus products. [10] Octyl acetate can be synthesized by the Fischer esterification of 1-octanol and acetic acid: CH 3 (CH 2) 7 OH + CH 3 CO 2 H → CH 3 (CH 2) 7 O 2 CCH 3 + H 2 O