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London dispersion forces (LDF, also known as dispersion forces, London forces, instantaneous dipole–induced dipole forces, fluctuating induced dipole bonds [1] or loosely as van der Waals forces) are a type of intermolecular force acting between atoms and molecules that are normally electrically symmetric; that is, the electrons are ...
The third and dominant contribution is the dispersion or London force (fluctuating dipole–induced dipole), which arises due to the non-zero instantaneous dipole moments of all atoms and molecules. Such polarization can be induced either by a polar molecule or by the repulsion of negatively charged electron clouds in non-polar molecules.
Hexane is a good example of a molecule with no polarity or highly electronegative atoms, yet is a liquid at room temperature due mainly to London dispersion forces. In this example, when one hexane molecule approaches another, a temporary, weak partially negative dipole on the incoming hexane can polarize the electron cloud of another, causing ...
London dispersion forces are also known as 'dispersion forces', 'London forces', or 'instantaneous dipole–induced dipole forces'. The strength of London dispersion forces is proportional to the polarizability of the molecule, which in turn depends on the total number of electrons and the area over which they are spread.
London dispersion forces arise from instantaneous dipoles between two nonpolar molecules close together. The random nature of electron orbit allows moments in which the charge distribution in a molecule is unevenly distributed, allowing an electrostatic attraction to another molecule with a temporary dipole. A larger molecule allows for a ...
Dispersion forces keep the molecule inert even while its core Si-Si bond lengthens. Similarly, the longest known Ge-Ge bond is found in t Bu 3 GeGe t Bu 3 and is also facilitated by dispersion stabilization. [19] Dispersion stabilization has also been invoked for (t BuC) 3 P, a main group analog of a hydrocarbon tetrahedrane. [20]
Keesom forces are the forces between the permanent dipoles of two polar molecules. [23]: 701 London dispersion forces are the forces between induced dipoles of different molecules. [23]: 703 There can also be an interaction between a permanent dipole in one molecule and an induced dipole in another molecule. [23]: 702
Ion–dipole interactions; The van der Waals forces, which consist of dipole–dipole, dipole–induced dipole, and induced dipole–induced dipole interactions. Which of these forces are at play depends on the molecular structure and properties of the solvent and solute.