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The hydrogen sulfide gas is biochemically oxidized in the presence of moisture to form sulfuric acid. The effect of sulfuric acid on concrete and steel surfaces exposed to severe wastewater environments can be devastating. [1] In the USA alone, corrosion causes sewer asset losses estimated at $14 billion per year. [2]
Example of flat piece of concrete having dislodged with corroded rebar underneath, Welland River bridge across Queen Elizabeth Way in Niagara Falls, Ontario. The expansion of the corrosion products (iron oxides) of carbon steel reinforcement structures may induce internal mechanical stress (tensile stress) that cause the formation of cracks and disrupt the concrete structure.
Oxidation of pyrite in clay formations in contact with concrete – this produces sulfuric acid which reacts with concrete. Bacterial activity in sewers – anaerobic sulfate reduction at work in the organic-rich sludges accumulated under water in the conduits produces hydrogen sulfide gas (H 2 S).
These metal sulfides, such as iron(II) sulfide, are often black or brown, leading to the color of sludge. Pyrrhotite is a waste product of the Desulfovibrio bacteria, a sulfate reducing bacteria. When eggs are cooked for a long time, the yolk's surface may turn green. This color change is due to iron(II) sulfide, which forms as iron from the ...
Oxide jacking has caused concrete spalling on walls of the Herbst Pavilion at Fort Mason Center in San Francisco. The expansive force of rusting, which may be called oxide jacking or rust burst, is a phenomenon that can cause damage to structures made of stone, masonry, concrete or ceramics, and reinforced with metal components.
Iron(II,III) sulfide is a blue-black (sometimes pinkish [citation needed]) chemical compound of iron and sulfur with formula Fe 3 S 4 or FeS·Fe 2 S 3, which is much similar to iron(II,III) oxide. It occurs naturally as the sulfide mineral greigite and is magnetic. It is a bio-mineral produced by and found in magnetotactic bacteria.