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For example, sulfuric acid (H 2 SO 4) is a diprotic acid. Since only 0.5 mol of H 2 SO 4 are needed to neutralize 1 mol of OH −, the equivalence factor is: feq (H 2 SO 4) = 0.5. If the concentration of a sulfuric acid solution is c (H 2 SO 4) = 1 mol/L, then its normality is 2 N. It can also be called a "2 normal" solution.
Fick's first law relates the diffusive flux to the gradient of the concentration. It postulates that the flux goes from regions of high concentration to regions of low concentration, with a magnitude that is proportional to the concentration gradient (spatial derivative), or in simplistic terms the concept that a solute will move from a region of high concentration to a region of low ...
Chemical oxygen demand. In environmental chemistry, the chemical oxygen demand (COD) is an indicative measure of the amount of oxygen that can be consumed by reactions in a measured solution. It is commonly expressed in mass of oxygen consumed over volume of solution, which in SI units is milligrams per liter (mg / L).
In the Arrhenius equation, the term activation energy (Ea) is used to describe the energy required to reach the transition state, and the exponential relationship k = A exp (−Ea/RT) holds. In transition state theory, a more sophisticated model of the relationship between reaction rates and the transition state, a superficially similar ...
A Stiff diagram, or Stiff pattern, is a graphical representation of chemical analyses, first developed by H.A. Stiff in 1951. It is widely used by hydrogeologists and geochemists to display the major ion composition of a water sample. A polygonal shape is created from four parallel horizontal axes extending on either side of a vertical zero ...
It breaks down an apparently unimolecular reaction into two elementary steps, with a rate constant for each elementary step. The rate law and rate equation for the entire reaction can be derived from the rate equations and rate constants for the two steps. The Lindemann mechanism is used to model gas phase decomposition or isomerization reactions.
Diffusion-controlled reaction. Diffusion-controlled (or diffusion-limited) reactions are reactions in which the reaction rate is equal to the rate of transport of the reactants through the reaction medium (usually a solution). [1] The process of chemical reaction can be considered as involving the diffusion of reactants until they encounter ...
For example, such a regulation might limit the concentration of NOx to 55 ppmv in a dry combustion exhaust gas corrected to 3 volume percent O 2. As another example, a regulation might limit the concentration of particulate matter to 0.1 grain per standard cubic foot (i.e., scf) of dry exhaust gas corrected to 12 volume percent CO 2.