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2 nh 3 + h 2 so 4 → (nh 4) 2 so 4 A mixture of ammonia gas and water vapor is introduced into a reactor that contains a saturated solution of ammonium sulfate and about 2% to 4% of free sulfuric acid at 60 °C.
Ammonium iron(II) sulfate, or Mohr's salt, is the inorganic compound with the formula (NH 4) 2 SO 4 ·Fe(SO 4)·6H 2 O.Containing two different cations, Fe 2+ and NH + 4, it is classified as a double salt of ferrous sulfate and ammonium sulfate.
Ammonium iron(III) sulfate, NH 4 Fe(SO 4) 2 ·12 H 2 O, or NH 4 [Fe(H 2 O) 6](SO 4) 2 ·6 H 2 O, also known as ferric ammonium sulfate (FAS) or iron alum, is a double salt in the class of alums, which consists of compounds with the general formula AB(SO 4) 2 · 12 H 2 O. [2] It has the appearance of weakly violet, octahedrical crystals.
2 NH 3 + SO 2 + H 2 O → (NH 4) 2 SO 3. Ammonium sulfite is produced in gas scrubbers, now obsolete, consisting of ammonium hydroxide to remove sulfur dioxide from emissions from power plants. The conversion is the basis of the Walther Process. The resulting ammonium sulfite can be air oxidized to give ammonium sulfate. [4]
It is commonly collected as a byproduct of the "acetone cyanohydrin route" to the commodity chemical methyl methacrylate. [1]It can also be obtained by hydrolysis of sulfamic acid in aqueous solution, which produces the salt in high purity:
Ammonium is a modified form of ammonia that has an extra hydrogen atom. It is a positively charged molecular ion with the chemical formula NH + 4 or [NH 4] +.It is formed by the addition of a proton (a hydrogen nucleus) to ammonia (NH 3).
Solid NH 2 OH can be collected by treatment with liquid ammonia. Ammonium sulfate, [NH 4] 2 SO 4, a side-product insoluble in liquid ammonia, is removed by filtration; the liquid ammonia is evaporated to give the desired product. [4] The net reaction is: 2 NO − 2 + 4 SO 2 + 6 H 2 O + 6 NH 3 → 4 SO 2− 4 + 6 [NH 4] + + 2 NH 2 OH. A base ...
2 (NH 3 OH) 2 SO 4 → 2 SO 3 + N 2 O + 2 NH 3 + 5 H 2 O. The reaction is exothermic above 138 °C, and is most exothermic at 177 °C. [3] Metals (especially copper, its alloys and its salts) catalyse the decomposition of hydroxylammonium sulfate. The instability of this compound is mainly due to the hydroxylammonium ion's weak nitrogen to ...