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The electrostatic double layer force decays in an exponential fashion. Due to the screening by the electrolyte, the range of the force is given by the Debye length and its strength by the surface potential (or surface charge density). This approximation turns out to be exact provided the plate-plate separation is large compared to the Debye ...
The total electrical double layer due to the formation of the counterion layers results in electrostatic screening of the wall charge and minimizes the Gibbs free energy of EDL formation. The thickness of the diffuse electric double layer is known as the Debye screening length /. At a distance of two Debye screening lengths the electrical ...
In surface science, a double layer (DL, also called an electrical double layer, EDL) is a structure that appears on the surface of an object when it is exposed to a fluid. The object might be a solid particle, a gas bubble, a liquid droplet, or a porous body. The DL refers to two parallel layers of charge surrounding the object.
The double-layer is like the dielectric layer in a conventional capacitor, but with the thickness of a single molecule. Using the early Helmholtz model to calculate the capacitance the model predicts a constant differential capacitance C d independent from the charge density, even depending on the dielectric constant ε and the charge layer ...
The Poisson–Boltzmann equation describes a model proposed independently by Louis Georges Gouy and David Leonard Chapman in 1910 and 1913, respectively. [3] In the Gouy-Chapman model, a charged solid comes into contact with an ionic solution, creating a layer of surface charges and counter-ions or double layer. [4]
Double layer (surface science), a structure that appears on the surface of an object when it is placed into a liquid; Double layer forces, which occur between charged objects across liquids; Double layer potential, a solution of Laplace's equation; Double layer suturing, two layers of sutures, first in a deep level of a tissue and then at a ...
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[1] [2] [3] There is a common source of all these effects—the so-called interfacial 'double layer' of charges. Influence of an external force on the diffuse layer generates tangential motion of a fluid with respect to an adjacent charged surface. This force might be electric, pressure gradient, concentration gradient, or gravity.