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Potential graphene applications include lightweight, thin, and flexible electric/photonics circuits, solar cells, and various medical, chemical and industrial processes enhanced or enabled by the use of new graphene materials, and favoured by massive cost decreases in graphene production. [1] [2] [3]
Graphene is commonly modified with oxygen- and nitrogen-containing functional groups and analyzed by infrared spectroscopy and X-ray photoelectron spectroscopy. However, the determination of structures of graphene with oxygen-[187] and nitrogen-[188] functional groups require the structures to be well controlled.
The onset temperature of reaction between the basal plane of single-layer graphene and oxygen gas is below 260 °C (530 K). [2] Graphene combusts at 350 °C (620 K). [3] Graphene is commonly modified with oxygen- and nitrogen-containing functional groups and analyzed by infrared spectroscopy and X-ray photoelectron spectroscopy.
A rapidly increasing list of graphene production techniques have been developed to enable graphene's use in commercial applications. [1]Isolated 2D crystals cannot be grown via chemical synthesis beyond small sizes even in principle, because the rapid growth of phonon density with increasing lateral size forces 2D crystallites to bend into the third dimension. [2]
The two-dimensional electron system in graphene can be tuned to either a 2DEG or 2DHG (2-D hole gas) by gating or chemical doping. This has been a topic of current research due to the versatile (some existing but mostly envisaged) applications of graphene. [2] A separate class of heterostructures that can host 2DEGs are oxides.
Graphene doped with various gaseous species (both acceptors and donors) can be returned to an undoped state by gentle heating in vacuum. [22] [24] Even for dopant concentrations in excess of 10 12 cm −2 carrier mobility exhibits no observable change. [24] Graphene doped with potassium in ultra-high vacuum at low temperature can reduce ...
Graphene quantum dots (GQDs) are graphene nanoparticles with a size less than 100 nm. Due to their exceptional properties such as low toxicity, stable photoluminescence , chemical stability and pronounced quantum confinement effect, GQDs are considered as a novel material for biological, opto-electronics, energy and environmental applications.
The air stability of graphene shows a clear thickness dependence: monolayer graphene is reactive to oxygen at 250 °C, strongly doped at 300 °C, and etched at 450 °C; in contrast, bulk graphite is not oxidized until 800 °C. [71] Atomically thin boron nitride has much better oxidation resistance than graphene.
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