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Fractional distillation. Fractional distillation is the separation of a mixture into its component parts, or fractions. Chemical compounds are separated by heating them to a temperature at which one or more fractions of the mixture will vaporize. It uses distillation to fractionate.
Fractionating column. A fractionating column or fractional column is equipment used in the distillation of liquid mixtures to separate the mixture into its component parts, or fractions, based on their differences in volatility. Fractionating columns are used in small-scale laboratory distillations as well as large-scale industrial distillations.
Fractionation at total reflux. The Fenske equation in continuous fractional distillation is an equation used for calculating the minimum number of theoretical plates required for the separation of a binary feed stream by a fractionation column that is being operated at total reflux (i.e., which means that no overhead product distillate is being withdrawn from the column).
Distillation. Laboratory model of a still. 1: The heat source to boil the mixture. 2: round-bottom flask containing the mixture to be boiled. 3: the head of the still. 4: mixture boiling-point thermometre. 5: the condenser of the still. 6: the cooling-water inlet of the condenser. 7: the cooling-water outlet of the condenser.
Such vapor–liquid equilibrium information is useful in designing columns for distillation, especially fractional distillation, which is a particular specialty of chemical engineers. [1] [2] [3] Distillation is a process used to separate or partially separate components in a mixture by boiling (vaporization) followed by condensation ...
McCabe–Thiele method. The McCabe–Thiele method is a technique that is commonly employed in the field of chemical engineering to model the separation of two substances by a distillation column. [1][2][3] It uses the fact that the composition at each theoretical tray is completely determined by the mole fraction of one of the two components.
Theoretical plate. A theoretical plate in many separation processes is a hypothetical zone or stage in which two phases, such as the liquid and vapor phases of a substance, establish an equilibrium with each other. Such equilibrium stages may also be referred to as an equilibrium stage, ideal stage, or a theoretical tray.
Ideal solution. An ideal solution or ideal mixture is a solution that exhibits thermodynamic properties analogous to those of a mixture of ideal gases. [1] The enthalpy of mixing is zero [2] as is the volume change on mixing by definition; the closer to zero the enthalpy of mixing is, the more "ideal" the behavior of the solution becomes.