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  2. Chemical polarity - Wikipedia

    en.wikipedia.org/wiki/Chemical_polarity

    Ionic bonds generally occur when the difference in electronegativity between the two atoms is greater than 2.0; Pauling based this classification scheme on the partial ionic character of a bond, which is an approximate function of the difference in electronegativity between the two bonded atoms. He estimated that a difference of 1.7 corresponds ...

  3. Ionic bonding - Wikipedia

    en.wikipedia.org/wiki/Ionic_bonding

    Thus, bonding is considered ionic where the ionic character is greater than the covalent character. The larger the difference in electronegativity between the two types of atoms involved in the bonding, the more ionic (polar) it is. Bonds with partially ionic and partially covalent character are called polar covalent bonds. For example, Na–Cl ...

  4. Dissociation (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Dissociation_(chemistry)

    Dissociation diagram of phosphoric acid Dissociation in chemistry is a general process in which molecules (or ionic compounds such as salts , or complexes ) separate or split into other things such as atoms, ions, or radicals , usually in a reversible manner.

  5. Chemical bond - Wikipedia

    en.wikipedia.org/wiki/Chemical_bond

    Ionic bonding leads to separate positive and negative ions. Ionic charges are commonly between −3e to +3e. Ionic bonding commonly occurs in metal salts such as sodium chloride (table salt). A typical feature of ionic bonds is that the species form into ionic crystals, in which no ion is specifically paired with any single other ion in a ...

  6. Valence bond theory - Wikipedia

    en.wikipedia.org/wiki/Valence_bond_theory

    For example, a bond between two s-orbital electrons is a sigma bond, because two spheres are always coaxial. In terms of bond order, single bonds have one sigma bond, double bonds consist of one sigma bond and one pi bond, and triple bonds contain one sigma bond and two pi bonds. However, the atomic orbitals for bonding may be hybrids.

  7. Pauling's rules - Wikipedia

    en.wikipedia.org/wiki/Pauling's_rules

    For typical ionic solids, the cations are smaller than the anions, and each cation is surrounded by coordinated anions which form a polyhedron.The sum of the ionic radii determines the cation-anion distance, while the cation-anion radius ratio + / (or /) determines the coordination number (C.N.) of the cation, as well as the shape of the coordinated polyhedron of anions.

  8. Hypervalent molecule - Wikipedia

    en.wikipedia.org/wiki/Hypervalent_molecule

    Phosphorus pentafluoride. There are 2 possible structures with an axial ionic bond, plus 3 possible structures with an equatorial ionic bond. For a hexacoordinate molecule such as sulfur hexafluoride, each of the six bonds is the same length. The rationalization described above can be applied to generate 15 resonance structures each with four ...

  9. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    Molecular geometries can be specified in terms of 'bond lengths', 'bond angles' and 'torsional angles'. The bond length is defined to be the average distance between the nuclei of two atoms bonded together in any given molecule. A bond angle is the angle formed between three atoms across at least two bonds.