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Iron(III) oxide or ferric oxide is the inorganic compound with the formula Fe 2 O 3. It occurs in nature as the mineral hematite , which serves as the primary source of iron for the steel industry. It is also known as red iron oxide , especially when used in pigments .
Ferric oxide, commonly called rust, is a very complicated material that contains iron(III). Iron(III) is found in many minerals and solids, e.g., oxide Fe 2 O 3 (hematite) and iron(III) oxide-hydroxide FeO(OH) are extremely insoluble reflecting their polymeric structure. Rust is a mixture of iron(III) oxide and oxide-hydroxide that usually ...
In Stock nomenclature, which is commonly used for inorganic compounds, the oxidation state is represented by a Roman numeral placed after the element name inside parentheses or as a superscript after the element symbol, e.g. Iron(III) oxide. The term oxidation was first used by Antoine Lavoisier to signify the reaction of a substance with oxygen.
Iron(II) complexes are less stable than iron(III) complexes but the preference for O-donor ligands is less marked, so that for example [Fe(NH 3) 6] 2+ is known while [Fe(NH 3) 6] 3+ is not. They have a tendency to be oxidized to iron(III) but this can be moderated by low pH and the specific ligands used. [72]
Iron oxides feature as ferrous or ferric or both. They adopt octahedral or tetrahedral coordination geometry. Only a few oxides are significant at the earth's surface, particularly wüstite, magnetite, and hematite. Oxides of Fe II. FeO: iron(II) oxide, wüstite; Mixed oxides of Fe II and Fe III. Fe 3 O 4: Iron(II,III) oxide, magnetite; Fe 4 O ...
The iron compounds produced on the largest scale in industry are iron(II) sulfate (FeSO 4 ·7H 2 O) and iron(III) chloride (FeCl 3). The former is one of the most readily available sources of iron(II), but is less stable to aerial oxidation than Mohr's salt ((NH 4) 2 Fe(SO 4) 2 ·6H 2 O). Iron(II) compounds tend to be oxidized to iron(III ...
Iron(III) oxide-hydroxide or ferric oxyhydroxide [2] is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH). The compound is often encountered as one of its hydrates, FeO(OH) ·n H 2 O [rust]. The monohydrate FeO(OH) · H 2 O is often referred to as iron(III) hydroxide Fe(OH) 3, [3] hydrated iron oxide, yellow iron oxide ...
Iron(III) is then reduced back to iron(II) by another molecule of hydrogen peroxide, forming a hydroperoxyl radical and a proton. The net effect is a disproportionation of hydrogen peroxide to create two different oxygen-radical species, with water (H + + OH − ) as a byproduct.