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  2. E1cB-elimination reaction - Wikipedia

    en.wikipedia.org/wiki/E1cB-elimination_reaction

    An example of the E1cB reaction mechanism in the degradation of a hemiketal under basic conditions. The E1cB elimination reaction is a type of elimination reaction which occurs under basic conditions, where the hydrogen to be removed is relatively acidic, while the leaving group (such as -OH or -OR) is a relatively poor one.

  3. Elimination reaction - Wikipedia

    en.wikipedia.org/wiki/Elimination_reaction

    Elimination reaction of cyclohexanol to cyclohexene with sulfuric acid and heat [1] An elimination reaction is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism. [2] The one-step mechanism is known as the E2 reaction, and the two-step mechanism is known as the E1 reaction ...

  4. Aldol condensation - Wikipedia

    en.wikipedia.org/wiki/Aldol_condensation

    A mechanism for aldol condensation in basic conditions, which occurs via enolate intermediates and E1CB elimination. The process begins when a free hydroxide (strong base) strips the highly acidic proton at the alpha carbon of the aldehyde. This deprotonation causes the electrons from the C–H bond to shift and create a new C–C pi bond.

  5. Ei mechanism - Wikipedia

    en.wikipedia.org/wiki/Ei_mechanism

    In organic chemistry, the E i mechanism (Elimination Internal/Intramolecular), also known as a thermal syn elimination or a pericyclic syn elimination, is a special type of elimination reaction in which two vicinal (adjacent) substituents on an alkane framework leave simultaneously via a cyclic transition state to form an alkene in a syn elimination. [1]

  6. Nucleophilic aromatic substitution - Wikipedia

    en.wikipedia.org/wiki/Nucleophilic_aromatic...

    S N Ar (addition-elimination) mechanism; aromatic S N 1 mechanism encountered with diazonium salts; benzyne mechanism (E1cB-Ad N) free radical S RN 1 mechanism; ANRORC mechanism; Vicarious nucleophilic substitution; The S N Ar mechanism is the most important of these. Electron withdrawing groups activate the ring towards nucleophilic attack.

  7. Federal employees told to remove pronouns from email ...

    www.aol.com/federal-employees-told-remove...

    Employees at multiple federal agencies were ordered to remove pronouns from their email signatures by Friday afternoon, according to internal memos obtained by ABC News that cited two executive ...

  8. 7 foods that kill and lower testosterone - AOL

    www.aol.com/7-foods-kill-lower-testosterone...

    Examples include high-fructose corn syrup, glucose, fructose, and raw sugar. Common sugar-sweetened drinks include soda, fruit juices, bottled iced teas, energy drinks, and sweetened coffee drinks

  9. Adenylosuccinate lyase - Wikipedia

    en.wikipedia.org/wiki/Adenylosuccinate_lyase

    Adenylosuccinate lyase belongs to the β-elimination superfamily, and as such its structure is a homotetramer . The monomer of adenylosuccinate lyase has three domains. In Thermotoga maritima , domain 1 contains 7 α-helices in residues 1-93, including the His68 which is highly conserved and was previously thought to be the catalytic acid in ...