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The tert-butyloxycarbonyl protecting group or tert-butoxycarbonyl protecting group [1] (BOC group) is an acid-labile protecting group used in organic synthesis. The BOC group can be added to amines under aqueous conditions using di- tert -butyl dicarbonate in the presence of a base such as sodium hydroxide :
The Boc group can be added to the amine under aqueous conditions using di-tert-butyl dicarbonate in the presence of a base such as sodium bicarbonate.Protection of the amine can also be accomplished in acetonitrile solution using 4-dimethylaminopyridine (DMAP) as the base.
The Boc/Bzl approach retains its usefulness in reducing peptide aggregation during synthesis. [28] In addition, Boc/benzyl SPPS may be preferred over the Fmoc/ tert- butyl approach when synthesizing peptides containing base-sensitive moieties (such as depsipeptides or thioester moeities), as treatment with base is required during the Fmoc ...
Process service agencies are third-party companies capable of granting BOC-3 filings. Process service agencies must employ or lease the services of individuals or entities within each state and be federally registered with the FMCSA in order to be able to grant a BOC-3. While BOC-3 filings are relatively uniform, the process agent companies ...
For that reason, I don’t see this being a high-scoring affair. In the end, Mahomes and the Chiefs find a way to pull out yet another one-score win." 2025 Super Bowl: Chiefs stats, scouting report.
From January 2008 to December 2012, if you bought shares in companies when John B. Hess joined the board, and sold them when he left, you would have a -17.6 percent return on your investment, compared to a -2.8 percent return from the S&P 500.
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