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A Maxwell material is the most simple model viscoelastic material showing properties of a typical liquid. It shows viscous flow on the long timescale, but additional elastic resistance to fast deformations. [1] It is named for James Clerk Maxwell who proposed the model in 1867. [2] [3] It is also known as a Maxwell fluid
The relaxation time for such an arrangement is given by = + +. Importantly, since the materials' conductivities are in general frequency dependent, this shows that the double layer composite generally has a frequency dependent relaxation time even if the individual layers are characterized by frequency independent permittivities.
Experimentally, stress relaxation is determined by step strain experiments, i.e. by applying a sudden one-time strain and measuring the build-up and subsequent relaxation of stress in the material (see figure), in either extensional or shear rheology. a) Applied step strain and b) induced stress as functions of time for a viscoelastic material.
The generalized Maxwell model, also known as the Wiechert model, is the most general form of the linear model for viscoelasticity. It takes into account that the relaxation does not occur at a single time, but at a distribution of times. Due to molecular segments of different lengths with shorter ones contributing less than longer ones, there ...
For instance, in simple steady shear, the Weissenberg number, often abbreviated as Wi or We, is defined as the shear rate ˙ times the relaxation time . Using the Maxwell model and the Oldroyd-B model, the elastic forces can be written as the first Normal force (N 1).
Vibrational energy relaxation, or vibrational population relaxation, is a process in which the population distribution of molecules in quantum states of high energy level caused by an external perturbation returns to the Maxwell–Boltzmann distribution. In solution, the process proceeds with intra- and intermolecular energy transfer. The ...
For this case only two components of the shear stress became non-zero: = ˙ and = ˙ where ˙ is the shear rate.. Thus, the upper-convected Maxwell model predicts for the simple shear that shear stress to be proportional to the shear rate and the first difference of normal stresses is proportional to the square of the shear rate, the second difference of normal stresses is always zero.
Often, the simpler Maxwell model and the Kelvin–Voigt model are used. These models often prove insufficient, however; the Maxwell model does not describe creep or recovery, and the Kelvin–Voigt model does not describe stress relaxation. SLS is the simplest model that predicts both phenomena.