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The vanadyl or oxovanadium(IV) cation, VO 2+, [1] is a functional group that is common in the coordination chemistry of vanadium. Complexes containing this functional group are characteristically blue and paramagnetic. A triple bond is proposed to exist between the V 4+ and O 2− centers. [2]
From left: [V(H 2 O) 6] 2+ (lilac), [V(H 2 O) 6] 3+ (green), [VO(H 2 O) 5] 2+ (blue) and [VO(H 2 O) 5] 3+ (yellow).. Vanadium compounds are compounds formed by the element vanadium (V). The chemistry of vanadium is noteworthy for the accessibility of the four adjacent oxidation states 2–5, whereas the chemistry of the other group 5 elements, niobium and tantalum, are somewhat more limited to ...
Vanadium(IV) oxide or vanadium dioxide is an inorganic compound with the formula VO 2.It is a dark blue solid. Vanadium(IV) dioxide is amphoteric, dissolving in non-oxidising acids to give the blue vanadyl ion, [VO] 2+ and in alkali to give the brown [V 4 O 9] 2− ion, or at high pH [VO 4] 4−. [4]
Vanadium(III) oxide is the inorganic compound with the formula V 2 O 3. It is a black solid prepared by reduction of V 2 O 5 with hydrogen or carbon monoxide. [3] [4] It is a basic oxide dissolving in acids to give solutions of vanadium (III) complexes. [4] V 2 O 3 has the corundum structure. [4]
V 2 O 5 + SO 2 → 2 VO 2 + SO 3. The catalyst is regenerated by oxidation with air: 4 VO 2 + O 2 → 2 V 2 O 5. Similar oxidations are used in the production of maleic anhydride: C 4 H 10 + 3.5 O 2 → C 4 H 2 O 3 + 4 H 2 O. Phthalic anhydride and several other bulk organic compounds are produced similarly.
Phases with the general formula V n O 2n−1 exist between VO 2 and V 2 O 3. [1] Called Magnéli phases for Arne Magnéli, [2] they are examples of crystallographic shear compounds based on the rutile structure. [1] Examples of Magnéli phases include V 4 O 7, V 5 O 9, V 6 O 11, V 7 O 13 and V 8 O 15. V 3 O 5 appears as the mineral oxyvanite ...
The V=O bond distance is 160 pm, about 50 pm shorter than the V–OH 2 bonds. In solution, the sulfate ion dissociates rapidly. Being widely available, vanadyl sulfate is a common precursor to other vanadyl derivatives, such as vanadyl acetylacetonate: [7] [V(O)(H 2 O) 4]SO 4 + 2 C 5 H 8 O 2 + Na 2 CO 3 → [V(O)(C 5 H 7 O 2) 2] + Na 2 SO 4 + 5 ...
Conventionally this ion is represented with a single double bond, however this is a resonance form as the ion is a regular tetrahedron with four equivalent oxygen atoms. Additionally a range of polyoxovanadate ions exist which include discrete ions and "infinite" polymeric ions. [ 2 ]