Search results
Results From The WOW.Com Content Network
This expression for the discriminant is often taken as a definition. It makes clear that if the polynomial has a multiple root, then its discriminant is zero, and that, in the case of real coefficients, if all the roots are real and simple, then the discriminant is positive.
Positive solvatochromism corresponds to a bathochromic shift (or red shift) with increasing solvent polarity. An example of positive solvatochromism is provided by 4,4'-bis(dimethylamino)fuchsone, which is orange in toluene, red in acetone. The main value of the concept of solvatochromism is the context it provides to predict colors of solutions.
The above rules stating that extrema are characterized (among critical points with a non-singular Hessian) by a positive-definite or negative-definite Hessian cannot apply here since a bordered Hessian can neither be negative-definite nor positive-definite, as = if is any vector whose sole non-zero entry is its first.
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
Furthermore, if the Jacobian determinant at p is positive, then f preserves orientation near p; if it is negative, f reverses orientation. The absolute value of the Jacobian determinant at p gives us the factor by which the function f expands or shrinks volumes near p; this is why it occurs in the general substitution rule.
In mathematics, a symmetric matrix with real entries is positive-definite if the real number is positive for every nonzero real column vector, where is the row vector transpose of . [1] More generally, a Hermitian matrix (that is, a complex matrix equal to its conjugate transpose) is positive-definite if the real number is positive for every nonzero complex column vector , where denotes the ...
There are various equivalent ways to define the determinant of a square matrix A, i.e. one with the same number of rows and columns: the determinant can be defined via the Leibniz formula, an explicit formula involving sums of products of certain entries of the matrix. The determinant can also be characterized as the unique function depending ...
The first description of cooperative binding to a multi-site protein was developed by A.V. Hill. [4] Drawing on observations of oxygen binding to hemoglobin and the idea that cooperativity arose from the aggregation of hemoglobin molecules, each one binding one oxygen molecule, Hill suggested a phenomenological equation that has since been named after him: