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For molecules with lone pairs, the bonding orbitals are isovalent hybrids since different fractions of s and p orbitals are mixed to achieve optimal bonding. Isovalent hybridization is used to explain bond angles of those molecules that is inconsistent with the generalized simple sp, sp 2 and sp 3 hybridization.
Nonpolar molecules such as methane can form clathrate hydrates with water, especially under high pressure. Although there is no hydrogen bonding between water and guest molecules when methane is the guest molecule of the clathrate, guest–host hydrogen bonding often forms when the guest is a larger organic molecule such as tetrahydrofuran .
Protons tunnel across a series of hydrogen bonds between hydronium ions and water molecules.. The Grotthuss mechanism (also known as proton jumping) is a model for the process by which an 'excess' proton or proton defect diffuses through the hydrogen bond network of water molecules or other hydrogen-bonded liquids through the formation and concomitant cleavage of covalent bonds involving ...
Water molecules stay close to each other , due to the collective action of hydrogen bonds between water molecules. These hydrogen bonds are constantly breaking, with new bonds being formed with different water molecules; but at any given time in a sample of liquid water, a large portion of the molecules are held together by such bonds. [61]
Methane clathrate block embedded in the sediment of hydrate ridge, off Oregon, USA. Clathrate hydrates, or gas hydrates, clathrates, or hydrates, are crystalline water-based solids physically resembling ice, in which small non-polar molecules (typically gases) or polar molecules with large hydrophobic moieties are trapped inside "cages" of hydrogen bonded, frozen water molecules.
The water molecules function as Lewis bases, donating a pair of electrons to the metal ion and forming a dative covalent bond with it. Typical examples are listed in the following table. Typical examples are listed in the following table.
A chaotropic agent is a molecule in water solution that can disrupt the hydrogen bonding network between water molecules (i.e. exerts chaotropic activity).This has an effect on the stability of the native state of other molecules in the solution, mainly macromolecules (proteins, nucleic acids) by weakening the hydrophobic effect.
Simulation studies have shown that the variation in solvation energy between the ions and the surrounding water molecules underlies the mechanism of the Hofmeister series. [ 11 ] [ 12 ] A quantum chemical investigation suggests an electrostatic origin to the Hofmeister series. [ 13 ]