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Sodium chlorate is an inorganic compound with the chemical formula Na ClO 3.It is a white crystalline powder that is readily soluble in water. It is hygroscopic.It decomposes above 300 °C to release oxygen [4] and leaves sodium chloride.
[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
Sodium perchlorate is the precursor to ammonium, potassium and lithium perchlorate salts, often taking advantage of their low solubility in water relative to NaClO 4 (209 g/(100 mL) at 25 °C). [ 6 ] It is used for denaturating proteins in biochemistry and in standard DNA extraction and hybridization reactions in molecular biology .
Lewis structures (or "Lewis dot structures") are flat graphical formulas that show atom connectivity and lone pair or unpaired electrons, but not three-dimensional structure. This notation is mostly used for small molecules. Each line represents the two electrons of a single bond. Two or three parallel lines between pairs of atoms represent ...
The density of the solution is 1.093 g/mL at 5% concentration, [22] and 1.21 g/mL at 14%, 20 °C. [23] Stoichiometric solutions are fairly alkaline, with pH 11 or higher [8] since the hypochlorite ion is a weak base: OCl − + H 2 O ⇌ HOCl + OH −. The following species and equilibria are present in NaOCl/NaCl solutions: [24] HOCl(aq) ⇌ H ...
A valence bond structure resembles a Lewis structure, but when a molecule cannot be fully represented by a single Lewis structure, multiple valence bond structures are used. Each of these VB structures represents a specific Lewis structure. This combination of valence bond structures is the main point of resonance theory.
For example, NH 3 is a Lewis base, because it can donate its lone pair of electrons. Trimethylborane [(CH 3) 3 B] is a Lewis acid as it is capable of accepting a lone pair. In a Lewis adduct, the Lewis acid and base share an electron pair furnished by the Lewis base, forming a dative bond. [1]
The chlorate ion cannot be satisfactorily represented by just one Lewis structure, since all the Cl–O bonds are the same length (1.49 Å in potassium chlorate [1]), and the chlorine atom is hypervalent. Instead, it is often thought of as a hybrid of multiple resonance structures: