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In statistical process control (SPC), the ¯ and R chart is a type of scheme, popularly known as control chart, used to monitor the mean and range of a normally distributed variables simultaneously, when samples are collected at regular intervals from a business or industrial process. [1]
A calibration curve plot showing limit of detection (LOD), limit of quantification (LOQ), dynamic range, and limit of linearity (LOL).. In analytical chemistry, a calibration curve, also known as a standard curve, is a general method for determining the concentration of a substance in an unknown sample by comparing the unknown to a set of standard samples of known concentration. [1]
For processes that produce homogeneous batches (e.g., chemical) where repeat measurements vary primarily because of measurement error; The "chart" actually consists of a pair of charts: one, the individuals chart, displays the individual measured values; the other, the moving range chart, displays the difference from one point to the next.
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CEP is not a good measure of accuracy when this distribution behavior is not met. Munitions may also have larger standard deviation of range errors than the standard deviation of azimuth (deflection) errors, resulting in an elliptical confidence region. Munition samples may not be exactly on target, that is, the mean vector will not be (0,0).
Provided the data are strictly positive, a better measure of relative accuracy can be obtained based on the log of the accuracy ratio: log(F t / A t) This measure is easier to analyze statistically and has valuable symmetry and unbiasedness properties.
The X-bar chart is always used in conjunction with a variation chart such as the ¯ and R chart or ¯ and s chart. The R-chart shows sample ranges (difference between the largest and the smallest values in the sample), while the s-chart shows the samples' standard deviation. The R-chart was preferred in times when calculations were performed ...