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  2. Aufbau principle - Wikipedia

    en.wikipedia.org/wiki/Aufbau_principle

    The rule then predicts the electron configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 9 4s 2, abbreviated [Ar] 3d 9 4s 2 where [Ar] denotes the configuration of argon, the preceding noble gas. However, the measured electron configuration of the copper atom is [Ar] 3d 10 4s 1. By filling the 3d subshell, copper can be in a lower energy state.

  3. Electron configuration - Wikipedia

    en.wikipedia.org/wiki/Electron_configuration

    It shows the ground state configuration in terms of orbital occupancy, but it does not show the ground state in terms of the sequence of orbital energies as determined spectroscopically. For example, in the transition metals, the 4s orbital is of a higher energy than the 3d orbitals; and in the lanthanides, the 6s is higher than the 4f and 5d.

  4. Hund's rules - Wikipedia

    en.wikipedia.org/wiki/Hund's_rules

    As an example, consider the ground state of silicon.The electron configuration of Si is 1s 2 2s 2 2p 6 3s 2 3p 2 (see spectroscopic notation).We need to consider only the outer 3p 2 electrons, for which it can be shown (see term symbols) that the possible terms allowed by the Pauli exclusion principle are 1 D , 3 P , and 1 S.

  5. Ground state - Wikipedia

    en.wikipedia.org/wiki/Ground_state

    The ground state of a quantum-mechanical system is its stationary state of lowest energy; the energy of the ground state is known as the zero-point energy of the system. An excited state is any state with energy greater than the ground state. In quantum field theory, the ground state is usually called the vacuum state or the vacuum. If more ...

  6. Hund's rule of maximum multiplicity - Wikipedia

    en.wikipedia.org/wiki/Hund's_Rule_of_Maximum...

    Hund's rule of maximum multiplicity is a rule based on observation of atomic spectra, which is used to predict the ground state of an atom or molecule with one or more open electronic shells. The rule states that for a given electron configuration, the lowest energy term is the one with the greatest value of spin multiplicity. [1]

  7. Bohr model - Wikipedia

    en.wikipedia.org/wiki/Bohr_model

    The Bohr model gives an incorrect value L=ħ for the ground state orbital angular momentum: The angular momentum in the true ground state is known to be zero from experiment. Although mental pictures fail somewhat at these levels of scale, an electron in the lowest modern "orbital" with no orbital momentum, may be thought of as not to revolve ...

  8. Term symbol - Wikipedia

    en.wikipedia.org/wiki/Term_symbol

    Neutral atoms of the chemical elements have the same term symbol for each column in the s-block and p-block elements, but differ in d-block and f-block elements where the ground-state electron configuration changes within a column, where exceptions to Hund's rules occur. Ground state term symbols for the chemical elements are given below.

  9. Electron configurations of the elements (data page) - Wikipedia

    en.wikipedia.org/wiki/Electron_configurations_of...

    Note that these electron configurations are given for neutral atoms in the gas phase, which are not the same as the electron configurations for the same atoms in chemical environments. In many cases, multiple configurations are within a small range of energies and the irregularities shown below do not necessarily have a clear relation to ...