Search results
Results From The WOW.Com Content Network
In organic chemistry, an azo coupling is an reaction between a diazonium compound (R−N≡N +) and another aromatic compound that produces an azo compound (R−N=N−R’).In this electrophilic aromatic substitution reaction, the aryldiazonium cation is the electrophile, and the activated carbon (usually from an arene, which is called coupling agent), serves as a nucleophile.
Azo pigments are similar in chemical structure to azo dyes, but they lack solubilizing groups. [8] Many so-called azo pigments are not strictly classifiable as azo compounds since they exist as keto hydrazide tautomers, which lack the -N=N- linkage. C.I. Pigment Yellow 12, an azo pigment (also classified as a diarylide pigment).
The following other wikis use this file: Usage on fi.wikipedia.org Diatsoniumsuolat; Atsokytkentä; Usage on hu.wikipedia.org Diazóniumvegyületek
English: Reaction scheme for the diazo coupling of benzenediazonium chloride with aniline, forming 4-(phenyldiazenyl)aniline (description copied from File:Azo-coupling-B-2D-skeletal.png) ACS standard.
A similar palladium cycle but with different scenes and actors is observed in the Wacker process. Heck Reaction Mechanism This cycle is not limited to vinyl compounds, in the Sonogashira coupling one of the reactants is an alkyne and in the Suzuki coupling the alkene is replaced by an aryl boronic acid and in the Stille reaction by an aryl ...
This method can also be used with primary diazoalkanes, to produce secondary α-diazo ketones. However, there are many limitations. Primary diazoalkanes undergo azo coupling to form azines; thus the reaction conditions must be altered such that acid chloride is added to a solution of diazoalkane and triethylamine at low temperature.
Image credits: dogswithjobs There’s a popular saying that cats rule the Internet, and research has even found that the 2 million cat videos on YouTube have been watched more than 25 billion ...
As the compound readily forms diazo compounds, it is used to make dyes and sulfa drugs. [4] This property is also used for the quantitative analysis of nitrate and nitrite ions by diazonium coupling reaction with N-(1-Naphthyl)ethylenediamine, resulting in an azo dye, and the concentration of nitrate or nitrite ions were deduced from the color intensity of the resulting red solution by ...