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Acid-neutralizing capacity or ANC in short is a measure for the overall buffering capacity against acidification of a solution, e.g. surface water or soil water.. ANC is defined as the difference between cations of strong bases and anions of strong acids (see below), or dynamically as the amount of acid needed to change the pH value from the sample's value to a chosen different value. [1]
Global variation in soil pH. Red = acidic soil. Yellow = neutral soil. Blue = alkaline soil. Black = no data. Soil pH is a measure of the acidity or basicity (alkalinity) of a soil. Soil pH is a key characteristic that can be used to make informative analysis both qualitative and quantitatively regarding soil characteristics.
In the case of citric acid, the overlap is extensive and solutions of citric acid are buffered over the whole range of pH 2.5 to 7.5. Calculation of the pH with a polyprotic acid requires a speciation calculation to be performed. In the case of citric acid, this entails the solution of the two equations of mass balance:
The degree to which a given amount of lime per unit of soil volume will increase soil pH depends on the buffer capacity of the soil (this is generally related to soil cation exchange capacity or CEC). Most acid soils are saturated with aluminum rather than hydrogen ions. Soil acidity generally results from hydrolysis of aluminum. [4]
Cation-exchange capacity (CEC) is a measure of how many cations can be retained on soil particle surfaces. [1] Negative charges on the surfaces of soil particles bind positively-charged atoms or molecules (cations), but allow these to exchange with other positively charged particles in the surrounding soil water. [ 2 ]
The same equation relating the concentrations of acid and base applies. The concept of neutralization is not limited to reactions in solution. For example, the reaction of limestone with acid such as sulfuric acid is also a neutralization reaction. [Ca,Mg]CO 3 (s) + H 2 SO 4 (aq) → (Ca 2+, Mg 2+)(aq) + SO 2− 4 (aq) + CO 2 (g) + H 2 O
Aluminum is one of the few elements capable of making soil more acidic. [22] This is achieved by aluminum taking hydroxide ions out of water, leaving hydrogen ions behind. [23] As a result, the soil is more acidic, which makes it unlivable for many plants. Another consequence of aluminum in soils is aluminum toxicity, which inhibits root growth ...
The resistance of soil to change in pH, as a result of the addition of acid or basic material, is a measure of the buffering capacity of a soil and (for a particular soil type) increases as the CEC increases.