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An ion trap, used for precision measurements of radium ions, inside a vacuum chamber. View ports surrounding the chamber allow laser light to be directed into the trap. An ion trap is a combination of electric and/or magnetic fields used to capture charged particles — known as ions — often in a system isolated from an external environment.
In experimental physics, a quadrupole ion trap or paul trap is a type of ion trap that uses dynamic electric fields to trap charged particles. They are also called radio frequency (RF) traps or Paul traps in honor of Wolfgang Paul , who invented the device [ 1 ] [ 2 ] and shared the Nobel Prize in Physics in 1989 for this work. [ 3 ]
A TOF mass spectrometer can also have a low-duty cycle when coupled with a continuous ion source. Combining an ion trap with a TOF mass analyzer can improve the duty cycle. Both 3D and linear traps have been combined with TOF mass analyzers. A trap can also add MSn capabilities to the system. [1]
For SSIMS the primary requirement is low primary ion flux density which results in extremely low secondary ion yield (10 −3 – 10 −8 atoms/cm³). Hence, there is a need to collect almost all the secondary ions. High transmission (0.5–1) of TOF maximizes the sensitivity (10 4 times that of quadrupole MS). Parallel detection together with ...
A sector instrument can be combined with a collision quadrupole and quadrupole mass analyzer to form a hybrid instrument. [1] A BEqQ configuration with a magnetic sector (B), electric sector (E), collision quadrupole (q) and m/z selection quadrupole (Q) have been constructed [2] [3] and an instrument with two electric sectors (BEEQ) has been described.
A reflectron (mass reflectron) is a type of time-of-flight mass spectrometer (TOF MS) that comprises a pulsed ion source, field-free region, ion mirror, and ion detector and uses a static or time dependent electric field in the ion mirror to reverse the direction of travel of the ions entering it.
The Electron beam ion trap (EBIT), based on the same principle, can produce up to bare uranium ions and can be used as an ion source as well. Heavy ions can also be generated with an ion gun which typically uses the thermionic emission of electrons to ionize a substance in its gaseous state.
However, the throughput of TOF detectors is limited; the detection is performed in a serial fashion (one ion in the detector at a time). The longer the TOF for ions, the better the time resolution (equivalent to energy resolution) will be. [16] TOF spectrometers that have an incorporated solid state detector must be confined to small solid angles.