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A basic chloride of lead, PbCl 2 ·Pb(OH) 2, is known as Pattinson's white lead and is used as pigment in white paint. [17] Lead paint is now banned as a health hazard in many countries by the White Lead (Painting) Convention, 1921. PbCl 2 is an intermediate in refining bismuth (Bi) ore.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
It is a yellow, oily liquid which is stable below 0 °C, and decomposes at 50 °C. [2] It has a tetrahedral configuration , with lead as the central atom. The Pb– Cl covalent bonds have been measured to be 247 pm and the bond energy is 243 kJ⋅mol −1 .
Pb 2 (OH) 2 (NO 3) 2 is the predominant species formed at low pH. At higher pH Pb 6 (OH) 5 (NO 3) is formed. [17] The cation [Pb 6 O(OH) 6] 4+ is unusual in having an oxide ion inside a cluster of 3 face-sharing PbO 4 tetrahedra. [18] There is no evidence for the formation of the hydroxide, Pb(OH) 2, in aqueous solution below pH 12.
2 PbO + PbS → 3 Pb + SO 2. Metallic lead is attacked (oxidized) only superficially by air, forming a thin layer of lead oxide that protects it from further oxidation. The metal is not attacked by sulfuric or hydrochloric acids. It dissolves in nitric acid with the evolution of nitric oxide gas to form dissolved Pb(NO 3) 2. 3 Pb + 8 H + + 8 NO −
A polar molecule has a net dipole as a result of the opposing charges (i.e. having partial positive and partial negative charges) from polar bonds arranged asymmetrically. Water (H 2 O) is an example of a polar molecule since it has a slight positive charge on one side and a slight negative charge on the other. The dipoles do not cancel out ...
Lead sesquioxide, Pb 2 O 3, which is a lead (II,IV) oxide as well (lead(II) metaplumbate(IV) [Pb 2+][PbO 2− 3]), reddish yellow Pb 12 O 19 , monoclinic, dark-brown or black crystals The so-called black lead oxide , which is a mixture of PbO and fine-powdered Pb metal and used in the production of lead–acid batteries .
Chlorate is the common name of the ClO − 3 anion, whose chlorine atom is in the +5 oxidation state.The term can also refer to chemical compounds containing this anion, with chlorates being the salts of chloric acid.