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Oxide jacking has caused concrete spalling on walls of the Herbst Pavilion at Fort Mason Center in San Francisco. The expansive force of rusting, which may be called oxide jacking or rust burst, is a phenomenon that can cause damage to structures made of stone, masonry, concrete or ceramics, and reinforced with metal components.
Example of flat piece of concrete having dislodged with corroded rebar underneath, Welland River bridge across Queen Elizabeth Way in Niagara Falls, Ontario. The expansion of the corrosion products (iron oxides) of carbon steel reinforcement structures may induce internal mechanical stress (tensile stress) that cause the formation of cracks and disrupt the concrete structure.
Steel and concrete have similar coefficients of thermal expansion, [2] so a concrete structural member reinforced with steel will experience minimal differential stress as the temperature changes. Other readily available types of rebar are manufactured of stainless steel , and composite bars made of glass fiber , carbon fiber , or basalt fiber .
(2) The thermal expansion coefficients of concrete and steel are so close (1.0 × 10 −5 to 1.5 × 10 −5 for concrete and 1.2 × 10 −5 for steel) that the thermal stress-induced damage to the bond between the two components can be prevented. (3) Concrete can protect the embedded steel from corrosion and high-temperature induced softening.
The process of pit nucleation is initiated by the depassivation of the protective oxide layer isolating the metal substrate from the aggressive solution. The depassivation of the protective oxide layer is the less properly understood step in pitting corrosion and its very local and random appearance probably its most enigmatic characteristic.
Rust scale forming and flaking off from a steel bar heated to its forging temperature of 1200°C. Rapid oxidation occurs when heated steel is exposed to air. Rust is a general name for a complex of oxides and hydroxides of iron, [4] which occur when iron or some alloys that contain iron are exposed to oxygen and moisture for a long period of ...
Common mistakes people make when removing rust include using chemicals that are too harsh, like hydrochloric acid and chlorine bleach, and not thoroughly cleaning and drying the metal surface ...
The initiation time is related to the rate at which carbonation propagates in the concrete cover thickness.Once that carbonation reaches the steel surface, altering the local pH value of the environment, the protective thin film of oxides on the steel surface becomes instable, and corrosion initiates involving an extended portion of the steel surface.