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Two common examples are cellulose, a main component of the cell wall in plants, and starch, a name derived from the Anglo-Saxon stercan, meaning to stiffen. [ 2 ] To name a polysaccharide composed of a single type of monosaccharide, that is a homopolysaccharide, the ending “-ose” of the monosaccharide is replaced with “-an”. [ 3 ]
Glycogen (black granules) in spermatozoa of a flatworm; transmission electron microscopy, scale: 0.3 μm. Glycogen is a multibranched polysaccharide of glucose that serves as a form of energy storage in animals, [2] fungi, and bacteria. [3] It is the main storage form of glucose in the human body.
Other uses for α-glucan have been developed based on its availability in bacteria. The accumulation of glycogen Neisseria polysacchera and other bacteria are able to use in α-glucan to catalyze glucose units to form α-1,4-glucan and liberating fructose in the process. To regulate carbohydrate metabolism, more resistant starch was necessary.
Glycogen is analogous to starch, a glucose polymer in plants, and is sometimes referred to as animal starch, [16] having a similar structure to amylopectin but more extensively branched and compact than starch. Glycogen is a polymer of α(1→4) glycosidic bonds linked with α(1→6)-linked branches.
In enzymology, a starch synthase (EC 2.4.1.21) is an enzyme that catalyzes the chemical reaction. ADP-glucose + (1,4-alpha-D-glucosyl) n ADP + (1,4-alpha-D-glucosyl) n+1 Thus, the two substrates of this enzyme are ADP-glucose and a chain of D-glucose residues joined by 1,4-alpha-glycosidic bonds, whereas its two products are ADP and an elongated chain of glucose residues.
B-type chains, making half of the branches, have two branch points, and all chains have the same length. E. Meléndez-Hevia, R. Meléndez and E. I. Canela (2000) "Glycogen Structure: an Evolutionary View", pp. 319–326 in Technological and Medical Implications of Metabolic Control Analysis (ed. A. Cornish-Bowden and M. L. Cárdenas), Kluwer Academic Publishers, Dordrecht
Starch phosphorylase is a form of phosphorylase similar to glycogen phosphorylase, except that it acts upon starch instead of glycogen.. The plant alpha-glucan phosphorylase, commonly called starch phosphorylase (EC 2.4.1.1), is largely known for the phosphorolytic degradation of starch.
For example, cellulose is an unbranched homopolysaccharide made up of glucose monomers connected via beta-glycosidic linkages; glycogen is a branched form, where the glucose monomers are joined by alpha-glycosidic linkages. Depending upon the molecules attached that are of the following types: