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Vinyl chloride is an organochloride with the formula H 2 C=CHCl. It is also called vinyl chloride monomer (VCM) or chloroethene. It is an important industrial chemical chiefly used to produce the polymer polyvinyl chloride (PVC). Vinyl chloride is a colourless flammable gas that has a sweet odor and is carcinogenic.
In the early 1970s, the carcinogenicity of vinyl chloride (usually called vinyl chloride monomer or VCM) was linked to cancers in workers in the polyvinyl chloride industry. Specifically workers in polymerization section of a B.F. Goodrich plant near Louisville, Kentucky , were diagnosed with liver angiosarcoma also known as hemangiosarcoma , a ...
Construction of the first phase of the Shintech Addis plant was completed in 2000, and the second in 2002. [19] [20] The company set up Asia Silicones Monomer Ltd. and Shin-Etsu Silicones Ltd. in Thailand during 2001 and in 2002, Shin-Etsu Chemical established Zhejiang Shin-Etsu High-Tech Chemical Co., Ltd in the Zhejiang Province of China for the production of silicon products.
Unsaturated monomers such as acrylates, vinyl chloride, butadiene and styrene require inhibitors for both processing and safe transport and storage. Many monomers are purified industrially by distillation, which can lead to thermally-initiated polymerisation.
Vinyl polymers are subject of several structural variations, which greatly expands the range of polymers and their applications. With the exception of polyethylene, vinyl polymers can arise from head-to-tail linking of monomers, head-to-head combined with tail-to-tail, or a mixture of those two patterns. Additionally the substituted carbon center in such polymers is stereogenic (a "chiral center")
Living cationic polymerization is a living polymerization technique involving cationic propagating species. [1] [2] It enables the synthesis of very well defined polymers (low molar mass distribution) and of polymers with unusual architecture such as star polymers and block copolymers and living cationic polymerization is therefore as such of commercial and academic interest.
Other polymers formed by cationic polymerization are homopolymers and copolymers of polyterpenes, such as pinenes (plant-derived products), that are used as tackifiers. In the field of heterocycles, 1,3,5-trioxane is copolymerized with small amounts of ethylene oxide to form the highly crystalline polyoxymethylene plastic.
The US OSHA limits vinyl chloride exposure of workers to no more than 1 ppm for eight hours or 5 ppm for 15 minutes. The US Environmental Protection Agency (EPA) and FDA limit vinyl chloride in drinking water to 0.002 ppm. Food (ingestion) is a trivial source of exposure. [citation needed]