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  2. Molecular orbital diagram - Wikipedia

    en.wikipedia.org/wiki/Molecular_orbital_diagram

    Diatomic molecules consist of a bond between only two atoms. They can be broken into two categories: homonuclear and heteronuclear. A homonuclear diatomic molecule is one composed of two atoms of the same element. Examples are H 2, O 2, and N 2. A heteronuclear diatomic molecule is composed of two atoms of two different elements.

  3. Triplet oxygen - Wikipedia

    en.wikipedia.org/wiki/Triplet_oxygen

    Molecules of triplet oxygen contain two unpaired electrons, making triplet oxygen an unusual example of a stable and commonly encountered diradical: [2] it is more stable as a triplet than a singlet. According to molecular orbital theory , the electron configuration of triplet oxygen has two electrons occupying two π molecular orbitals (MOs ...

  4. Diatomic molecule - Wikipedia

    en.wikipedia.org/wiki/Diatomic_molecule

    A space-filling model of the diatomic molecule dinitrogen, N 2. Diatomic molecules (from Greek di- 'two') are molecules composed of only two atoms, of the same or different chemical elements. If a diatomic molecule consists of two atoms of the same element, such as hydrogen (H 2) or oxygen (O 2), then it is said to be homonuclear.

  5. Magnetochemistry - Wikipedia

    en.wikipedia.org/wiki/Magnetochemistry

    Molecular compounds that contain one or more unpaired electrons are paramagnetic. The magnitude of the paramagnetism is expressed as an effective magnetic moment, μ eff . For first-row transition metals the magnitude of μ eff is, to a first approximation, a simple function of the number of unpaired electrons, the spin-only formula.

  6. Oxygen - Wikipedia

    en.wikipedia.org/wiki/Oxygen

    2 molecules are paramagnetic. That is, they impart magnetic character to oxygen when it is in the presence of a magnetic field, because of the spin magnetic moments of the unpaired electrons in the molecule, and the negative exchange energy between neighboring O 2 molecules. [28]

  7. Molecular orbital theory - Wikipedia

    en.wikipedia.org/wiki/Molecular_orbital_theory

    In chemistry, molecular orbital theory (MO theory or MOT) is a method for describing the electronic structure of molecules using quantum mechanics. It was proposed early in the 20th century. The MOT explains the paramagnetic nature of O 2, which valence bond theory cannot explain.

  8. Paramagnetism - Wikipedia

    en.wikipedia.org/wiki/Paramagnetism

    Small molecules can be stable in radical form, oxygen O 2 is a good example. Such systems are quite rare because they tend to be rather reactive. Dilute systems. Dissolving a paramagnetic species in a diamagnetic lattice at small concentrations, e.g. Nd 3+ in CaCl 2 will

  9. Singlet oxygen - Wikipedia

    en.wikipedia.org/wiki/Singlet_oxygen

    The lowest excited state of the diatomic oxygen molecule is a singlet state. It is a gas with physical properties differing only subtly from those of the more prevalent triplet ground state of O 2 . In terms of its chemical reactivity, however, singlet oxygen is far more reactive toward organic compounds.