Search results
Results From The WOW.Com Content Network
Reducing agents can be ranked by increasing strength by ranking their reduction potentials. Reducers donate electrons to (that is, "reduce") oxidizing agents, which are said to "be reduced by" the reducer. The reducing agent is stronger when it has a more negative reduction potential and weaker when it has a more positive reduction potential.
The following table provides the reduction potentials of the indicated reducing agent at 25 °C. For example, among sodium (Na) metal, chromium (Cr) metal, cuprous (Cu + ) ion and chloride (Cl − ) ion, it is Na metal that is the strongest reducing agent while Cl − ion is the weakest; said differently, Na + ion is the weakest oxidizing agent ...
The activity coefficients and are included in the formal potential ′, and because they depend on experimental conditions such as temperature, ionic strength, and pH, ′ cannot be referred as an immuable standard potential but needs to be systematically determined for each specific set of experimental conditions.
The central metal (usually B vs Al) strongly influences reducing agent's strength. Aluminum hydrides are more nucleophilic and better reducing agents relative to borohydrides. [5] The relatively weak reducer sodium borohydride is typically used for reducing ketones and aldehydes. It tolerates many functional groups (nitro group, nitrile, ester ...
The data below tabulates standard electrode potentials (E°), in volts relative to the standard hydrogen electrode (SHE), at: . Temperature 298.15 K (25.00 °C; 77.00 °F); ...
Standard electrode potentials offer a quantitative measure of the power of a reducing agent, rather than the qualitative considerations of other reactive series. However, they are only valid for standard conditions: in particular, they only apply to reactions in aqueous solution. Even with this proviso, the electrode potentials of lithium and ...
Like other borohydrides, reductions are effected in two steps: delivery of the hydride equivalent to give the lithium alkoxide followed by hydrolytic workup:
TCEP is often used as a reducing agent to break disulfide bonds within and between proteins as a preparatory step for gel electrophoresis.. Compared to the other two most common agents used for this purpose (dithiothreitol and β-mercaptoethanol), TCEP has the advantages of being odorless, a more powerful reducing agent, an irreversible reducing agent (in the sense that TCEP does not ...