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The torr (symbol: Torr) is a unit of pressure based on an absolute scale, defined as exactly 1 / 760 of a standard atmosphere (101325 Pa). Thus one torr is exactly 101325 / 760 pascals (≈ 133.32 Pa).
The following table lists the Van der Waals constants (from the Van der Waals equation) for a number of common gases and volatile liquids. [ 1 ] To convert from L 2 b a r / m o l 2 {\displaystyle \mathrm {L^{2}bar/mol^{2}} } to L 2 k P a / m o l 2 {\displaystyle \mathrm {L^{2}kPa/mol^{2}} } , multiply by 100.
The standard atmosphere was originally defined as the pressure exerted by a 760 mm column of mercury at 0 °C (32 °F) and standard gravity (g n = 9.806 65 m/s 2). [2] It was used as a reference condition for physical and chemical properties, and the definition of the centigrade temperature scale set 100 °C as the boiling point of water at this pressure.
In these equations, g 0, M and R * are each single-valued constants, while P, L, T, and h are multivalued constants in accordance with the table below. The values used for M , g 0 , and R * are in accordance with the U.S. Standard Atmosphere , 1976, and the value for R * in particular does not agree with standard values for this constant. [ 2 ]
The van der Waals equation is a mathematical formula that describes the behavior of real gases.It is an equation of state that relates the pressure, temperature, and molar volume in a fluid.
Valid results within the quoted ranges from most equations are included in the table for comparison. A conversion factor is included into the original first coefficients of the equations to provide the pressure in pascals (CR2: 5.006, SMI: -0.875). Ref. SMI uses temperature scale ITS-48.
The table below lists a few of them, but there are more. Some of these organizations used other standards in the past. For example, IUPAC has, since 1982, defined standard reference conditions as being 0 °C and 100 kPa (1 bar), in contrast to its old standard of 0 °C and 101.325 kPa (1 atm). [2]
The compressibility factor at the critical point, which is defined as =, where the subscript indicates physical quantities measured at the critical point, is predicted to be a constant independent of substance by many equations of state. The table below for a selection of gases uses the following conventions: