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  2. Allyl group - Wikipedia

    en.wikipedia.org/wiki/Allyl_group

    All feature three contiguous sp²-hybridized carbon centers and all derive stability from resonance. [6] Each species can be presented by two resonance structures with the charge or unpaired electron distributed at both 1,3 positions. Resonance structure of the allyl anion. The cation is identical, but carries an opposite-sign charge. [7]

  3. Corey–House synthesis - Wikipedia

    en.wikipedia.org/wiki/Corey–House_synthesis

    The scope of the Corey-House synthesis is exceptionally broad, and a range of lithium diorganylcuprates (R 2 CuLi, R = 1°, 2°, or 3° alkyl, aryl, or alkenyl) and organyl (pseudo)halides (RX, R = methyl, benzylic, allylic, 1°, or cyclic 2° alkyl, aryl, or alkenyl and X = Br, I, OTs, or OTf; X = Cl is marginal) will undergo coupling as the nucleophilic and electrophilic coupling partners ...

  4. Finkelstein reaction - Wikipedia

    en.wikipedia.org/wiki/Finkelstein_reaction

    Vinyl, aryl and tertiary alkyl halides are unreactive; as a result, the reaction of NaI in acetone can be used as a qualitative test to determine which of the aforementioned classes an unknown alkyl halide belongs to, with the exception of alkyl iodides, as they yield the same product upon substitution.

  5. β-Carbon elimination - Wikipedia

    en.wikipedia.org/wiki/Β-Carbon_elimination

    β-Carbon elimination (beta-carbon elimination) is a type of reaction in organometallic chemistry wherein an allyl ligand bonded to a metal center is broken into the corresponding metal-bonded alkyl (aryl) ligand and an alkene. [1] It is a subgroup of elimination reactions.

  6. β-Hydride elimination - Wikipedia

    en.wikipedia.org/wiki/Β-Hydride_elimination

    β-Hydride elimination is a reaction in which a metal-alkyl centre is converted into the corresponding metal-hydride-alkene. [1] β-Hydride elimination can also occur for many alkoxide complexes as well. The main requirements are that the alkyl group possess a C-H bond β to the metal and that the metal be coordinatively unsaturated.

  7. Vinyl sulfone dyes - Wikipedia

    en.wikipedia.org/wiki/Vinyl_sulfone_dyes

    Vinyl sulfone dyes are reactive dyes comprising a vinyl sulfone group as reactive group (a fiber-bonding site of the reactive dye, "reactive hook"). Due to the relatively high reactivity of the vinyl sulfone group with water (residual moisture, air humidity), it is present in many commercial products in a protected form.

  8. Metal–halogen exchange - Wikipedia

    en.wikipedia.org/wiki/Metal–halogen_exchange

    Lithium–halogen exchange is frequently used to prepare vinyl-, aryl- and primary alkyllithium reagents. Vinyl halides usually undergo lithium–halogen exchange with retention of the stereochemistry of the double bond. [2] The presence of alkoxyl or related chelating groups accelerates lithium–halogen exchange. [3]

  9. Electrophilic aromatic substitution - Wikipedia

    en.wikipedia.org/wiki/Electrophilic_aromatic...

    The net result is the replacement of H by E in the aryl ring (3). Occasionally, other electrofuges (groups that can leave without their electron pair) beside H + will depart to reestablish aromaticity; these species include silyl groups (as SiR 3 +), the carboxy group (as CO 2 + H +), the iodo group (as I +), and tertiary alkyl groups like t ...