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The quantum concentration n Q is the particle concentration (i.e. the number of particles per unit volume) of a system where the interparticle distance is equal to the thermal de Broglie wavelength. Quantum effects become appreciable when the particle concentration is greater than or equal to the quantum concentration, which is defined as: [ 1 ]
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
Several sources [2] [12] [3] replace nσ λ with k λ r, where k λ is the absorption coefficient per unit density and r is the density of the gas. The absorption coefficient for spectral flux (a beam of radiation with a single wavelength, [W/m 2 /μm]) differs from the absorption coefficient for spectral intensity [W/sr/m 2 /μm] used in ...
Flux F through a surface, dS is the differential vector area element, n is the unit normal to the surface. Left: No flux passes in the surface, the maximum amount flows normal to the surface.
Using the carrier concentration equations given above, the mass action law can be stated as = =, where E g is the band gap energy given by E g = E c − E v. The above equation holds true even for lightly doped extrinsic semiconductors as the product n p {\displaystyle np} is independent of doping concentration.
In this system, the molecules tend to move from areas with high concentration to low concentration, until eventually, the concentration is the same everywhere. The microscopic explanation for this is based on kinetic theory and the random motion of molecules. However, it is simpler to describe the process in terms of chemical potentials: For a ...
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
In chemistry and physics, the dimensionless mixing ratio is the abundance of one component of a mixture relative to that of all other components. The term can refer either to mole ratio (see concentration ) or mass ratio (see stoichiometry ).