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Sulfanilamide (also spelled sulphanilamide) is a sulfonamide antibacterial drug. Chemically, it is an organic compound consisting of an aniline derivatized with a sulfonamide group. [1] Powdered sulfanilamide was used by the Allies in World War II to reduce infection rates and contributed to a dramatic reduction in mortality rates compared to ...
In organosulfur chemistry, sulfinamide is a functional group with the structure R−S(O)−NR 2 (where R = alkyl or aryl). [1] This functionality is composed of a sulfur - carbon ( S−C ) single bond , a sulfur- nitrogen ( S−N ) single bond , and a sulfur-oxygen (S-O) bond (see Sulfoxide for the nature of this bond) [ 2 ] .
In this example, the reactants are aniline, triethylamine (Et 3 N, Et = ethyl group), and iodine. Sulfur dioxide is believed to be activated through a series of intermediates: Et 3 N− + −I −, Et 3 N−I + −I − 3 and Et 3 N + −SO − 2. The sulfamide functional group is an increasingly common structural feature used in medicinal ...
Skeletal structural formula of Vitamin B 12.Many organic molecules are too complicated to be specified by a molecular formula.. The structural formula of a chemical compound is a graphic representation of the molecular structure (determined by structural chemistry methods), showing how the atoms are connected to one another. [1]
Sulfenamides have been characterized by X-ray crystallography.The S-N bond in sulfenamides is a chiral axis that leads to formation of diastereomeric compounds. The existence of these distinct stereoisomers is due to the formation of a partial double bond between either sulfur or nitrogen's lone pair and the other atom's antibonding orbitals. [1]
Chemical structure of a generic acylsulfonamide. Acylsulfonamide is a functional group in organic chemistry that is sometimes used in medicinal chemistry. [1] It consists of a sulfonamide group (SO 2 NH) linked to an acyl group (RCO), forming the structure R 1-CO-NH-SO 2-R 2.