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General ester of phosphonic acid; in fact, the phosphorus has a formal charge of +1, the oxygen above it has a formal charge of −1, and the bond between them is single. In organic chemistry, phosphonates or phosphonic acids are organophosphorus compounds containing C−PO(OR) 2 groups, where R is an organic group (alkyl, aryl).
Pages in category "Phosphonate esters" The following 18 pages are in this category, out of 18 total. This list may not reflect recent changes. A. Armine (chemical) B.
Organophosphate flame retardants are part of a wider family of phosphorus-based agents which include organic phosphonate and phosphinate esters, in addition to inorganic salts. [ 56 ] [ 57 ] When some prominent brominated flame retardant were banned in the early 2000s phosphorus-based agents were promoted as safer replacements.
Phosphite esters with tertiary alkyl halide groups can undergo the reaction, which would be unexpected if only an S N 2 mechanism was operating. Further support for this S N 1 type mechanism comes from the use of the Arbuzov reaction in the synthesis of neopentyl halides, a class of compounds that are notoriously unreactive towards S N 2 reactions.
Phosphites are oxidized to phosphate esters: P(OR) 3 + [O] → OP(OR) 3. This reaction underpins the commercial use of some phosphite esters as stabilizers in polymers. [6] Alkyl phosphite esters are used in the Perkow reaction for the formation of vinyl phosphonates, and in the Michaelis–Arbuzov reaction to form phosphonates.
Phosphonates are esters of phosphonic acid and have the general formula RP(=O)(OR') 2. Phosphonates have many technical applications, a well-known member being glyphosate, better known as Roundup. With the formula (HO) 2 P(O)CH 2 NHCH 2 CO 2 H, this derivative of glycine is one of the most widely used herbicides.
This nomenclature is commonly reserved for substituted derivatives, that is, organic group bonded to phosphorus, not simply an ester. For example, (CH 3 )PO(OH) 2 is " methylphosphonic acid ", which may of course form "methyl phosphonate " esters .
Phosphonates are salts (M 2 HPO 3) or esters (OP(OR) 2 R) of phosphonic acid Wikimedia Commons has media related to Phosphonates . The main article for this category is Phosphonate .