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This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
2-Ethylhexanol (abbreviated 2-EH) is an organic compound with the chemical formula C H 3 CH 2 CH 2 CH 2 CH(CH 2 CH 3)CH 2 OH.It is a branched, eight-carbon chiral alcohol.It is a colorless liquid that is poorly soluble in water but soluble in most organic solvents.
A well-known example of a positive azeotrope is an ethanol–water mixture (obtained by fermentation of sugars) consisting of 95.63% ethanol and 4.37% water (by mass), which boils at 78.2 °C. [10] Ethanol boils at 78.4 °C, water boils at 100 °C, but the azeotrope boils at 78.2 °C, which is lower than either of its constituents. [11]
In azeotropic distillation the volatility of the added component is the same as the mixture, and a new azeotrope is formed with one or more of the components based on differences in polarity. [2] If the material separation agent is selected to form azeotropes with more than one component in the feed then it is referred to as an entrainer.
Stability of residue curves in the vicinity of binary azeotropes. Pure components and azeotropic points are called nodes. Three different types are possible: Stable node: This is the pure component or the azeotropic point with the highest boiling temperature and lowest vapor pressure in a distillation region. All residue curves end at stable nodes.
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In industry the butanol-water mixture is separated with this technique. At the previous case the binary system forms already a heterogeneous azeotrope. The other application of the heteroazeotropic distillation is the separation of a binary system (A-B) forming a homogeneous azeotrope.
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