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Formal charges in ozone and the nitrate anion. In chemistry, a formal charge (F.C. or q*), in the covalent view of chemical bonding, is the hypothetical charge assigned to an atom in a molecule, assuming that electrons in all chemical bonds are shared equally between atoms, regardless of relative electronegativity.
Partial charges are created due to the asymmetric distribution of electrons in chemical bonds. For example, in a polar covalent bond like HCl, the shared electron oscillates between the bonded atoms. The resulting partial charges are a property only of zones within the distribution, and not the assemblage as a whole.
When charged particles move in electric and magnetic fields the following two laws apply: Lorentz force law: = (+),; Newton's second law of motion: = =; where F is the force applied to the ion, m is the mass of the particle, a is the acceleration, Q is the electric charge, E is the electric field, and v × B is the cross product of the ion's velocity and the magnetic flux density.
Mulliken charges arise from the Mulliken population analysis [1] [2] and provide a means of estimating partial atomic charges from calculations carried out by the methods of computational chemistry, particularly those based on the linear combination of atomic orbitals molecular orbital method, and are routinely used as variables in linear regression (QSAR [3]) procedures. [4]
Charge number (denoted z) is a quantized and dimensionless quantity derived from electric charge, with the quantum of electric charge being the elementary charge (e, constant). The charge number equals the electric charge ( q , in coulombs ) divided by the elementary charge: z = q / e .
A noteworthy example is electrophoresis, where a charged particle suspended in a media will move as a result of an applied electrical field. [17] Electrophoresis is widely used in biochemistry to distinguish molecules, such as proteins, based on size and charge. Other examples include electro-osmosis, sedimentation potential, and streaming ...
An example provided in Slater's original paper is for the iron atom which has nuclear charge 26 and electronic configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 6 4s 2.The screening constant, and subsequently the shielded (or effective) nuclear charge for each electron is deduced as: [1]
As an application example, the steady-state space-charge-limited current across a piece of intrinsic silicon with a charge-carrier mobility of 1500 cm 2 /V-s, a relative dielectric constant of 11.9, an area of 10 −8 cm 2 and a thickness of 10 −4 cm can be calculated by an online calculator to be 126.4 μA at 3 V. Note that in order for this ...