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Unlike for hydrogen, a closed-form solution to the Schrödinger equation for the helium atom has not been found. However, various approximations, such as the Hartree–Fock method, can be used to estimate the ground state energy and wavefunction of the atom. Historically, the first such helium spectrum calculation was done by Albrecht Unsöld ...
The unusual stability of the helium-4 nucleus is also important cosmologically: it explains the fact that in the first few minutes after the Big Bang, as the "soup" of free protons and neutrons which had initially been created in about 6:1 ratio cooled to the point that nuclear binding was possible, almost all first compound atomic nuclei to ...
Atoms can be excited by heat, electricity, or light. The hydrogen atom provides a simple example of this concept.. The ground state of the hydrogen atom has the atom's single electron in the lowest possible orbital (that is, the spherically symmetric "1s" wave function, which, so far, has been demonstrated to have the lowest possible quantum numbers).
Helium is the smallest and the lightest noble gas and one of the most unreactive elements, so it was commonly considered that helium compounds cannot exist at all, or at least under normal conditions. [1] Helium's first ionization energy of 24.57 eV is the highest of any element. [2]
The 4 Π g state has a 1σ 2 g 1σ u 2σ g 2π u electronic configuration, its electron affinity E is 0.18±0.03 eV, and its lifetime is 135±15 μsec; only the v=0 vibrational state is responsible for this long-lived state. [21] The molecular helium anion is also found in liquid helium that has been excited by electrons with an energy level ...
Any other configuration is an excited state. As an example, the ground state configuration of the sodium atom is 1s 2 2s 2 2p 6 3s 1, as deduced from the Aufbau principle (see below). The first excited state is obtained by promoting a 3s electron to the 3p subshell, to obtain the 1s 2 2s 2 2p 6 3p 1 configuration, abbreviated as the 3p level ...
Thus, in the helium atom, Hund's first rule correctly predicts that the 1s2s triplet state (3 S) is lower than the 1s2s singlet (1 S). Similarly for organic molecules, the same rule predicts that the first triplet state (denoted by T 1 in photochemistry) is lower than the first excited singlet state (S 1), which is generally correct.
[169] [170] Hafnium was the last stable element to be discovered (noting however the difficulties regarding the discovery of rhenium). 43 Technetium: 1937 C. Perrier and E. Segrè: 1937 C. Perrier & E. Segrè The two discovered a new element in a molybdenum sample that was used in a cyclotron, the first element to be discovered by synthesis. It ...