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This is electron-releasing character and is indicated by the +I effect. In short, alkyl groups tend to give electrons, leading to the induction effect. However, such an effect has been questioned. [2] As the induced change in polarity is less than the original polarity, the inductive effect rapidly dies out and is significant only over a short ...
In the high-temperature power stage, expanding high pressure hydrogen from the compression stage converts the heat energy into electrical energy via the MEA. As the high-temperature, high pressure hydrogen is forced through the PEM it is ionized, producing protons and electrons. The protons pass through the membrane while the electrodes expel ...
An electric effect influences the structure, reactivity, or properties of a molecule but is neither a traditional bond nor a steric effect. [1] In organic chemistry , the term stereoelectronic effect is also used to emphasize the relation between the electronic structure and the geometry ( stereochemistry ) of a molecule.
These mechanisms arise from the interaction between the electric fields and charged particles or polarization effects within the fluid. [2] The generation and movement of charge carriers (ions) in a fluid subjected to an electric field are the underlying physics of all EHD-based technologies.
An electron donating group (EDG) or electron releasing group (ERG, Z in structural formulas) is an atom or functional group that donates some of its electron density into a conjugated π system via resonance (mesomerism) or inductive effects (or induction)—called +M or +I effects, respectively—thus making the π system more nucleophilic.
An electromagnetic pump is a pump that moves liquid metal, molten salt, brine, or other electrically conductive liquid using electromagnetism. A magnetic field is set at right angles to the direction the liquid moves in, and a current is passed through it. This causes an electromagnetic force that moves the liquid.
This effect is depicted in scheme 3, where, in a para substituted arene 1a, one resonance structure 1b is a quinoid with positive charge on the X substituent, releasing electrons and thus destabilizing the Y substituent. This destabilizing effect is not possible when X has a meta orientation. Scheme 3. Hammett Inductive Mesomeric Effects
The alkaline fuel cell (AFC) or hydrogen-oxygen fuel cell was designed and first demonstrated publicly by Francis Thomas Bacon in 1959. It was used as a primary source of electrical energy in the Apollo space program. [41] The cell consists of two porous carbon electrodes impregnated with a suitable catalyst such as Pt, Ag, CoO, etc.